Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6250
Authors: | Bengasi, Giuseppe Quétu, Louise Baba, Kamal Ost, Alexander Cosas Fernandes, João P. Grysan, Patrick Heinze, Katja Boscher, Nicolas D. |
Title: | Constitution and conductivity of metalloporphyrin tapes |
Online publication date: | 9-Aug-2021 |
Year of first publication: | 2020 |
Language: | english |
Abstract: | Metalloporphyrin tapes form in a solvent-free oxidative chemical vapor deposition process on glass substrates. The metal center (M = NiII, CuII, ZnII, CoII, PdII, FeIIICl, 2H) in the 5,15-disubstituted porphyrin monomer affects the initial C–C coupling step and consequently the formation of triply or doubly linked porphyrin tapes as well as the interchain interaction in the tape as shown by optical spectroscopy, high resolution mass spectrometry and X-ray photoelectron spectroscopy. Optical spectroscopy and conductive atomic force microscopy reveal that these factors influence the near-infrared absorbance and the electrical conductivity of the films. Consequently, the metal ion of the metalloporphyrin allows tuning of the macroscopic properties of the thin films composed of metalloporphyrin tapes. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-6250 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | European journal of inorganic chemistry 20 |
Pages or article number: | 1938 1945 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2020 |
ISSN: | 1099-0682 |
Publisher URL: | https://doi.org/10.1002/ejic.202000243 |
Publisher DOI: | 10.1002/ejic.202000243 |
Appears in collections: | JGU-Publikationen |
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![]() | bengasi_giuseppe-constitution_a-20210804000629598.pdf | 1.62 MB | Adobe PDF | View/Open |