Constitution and conductivity of metalloporphyrin tapes

Bengasi, Giuseppe; Quétu, Louise; Baba, Kamal; Ost, Alexander; Cosas Fernandes, João P.; Grysan, Patrick; Heinze, Katja; Boscher, Nicolas D.

Constitution and conductivity of metalloporphyrin tapes

dc.contributor.author	Bengasi, Giuseppe
dc.contributor.author	Quétu, Louise
dc.contributor.author	Baba, Kamal
dc.contributor.author	Ost, Alexander
dc.contributor.author	Cosas Fernandes, João P.
dc.contributor.author	Grysan, Patrick
dc.contributor.author	Heinze, Katja
dc.contributor.author	Boscher, Nicolas D.
dc.date.accessioned	2021-08-09T09:20:31Z
dc.date.available	2021-08-09T09:20:31Z
dc.date.issued	2020
dc.description.abstract	Metalloporphyrin tapes form in a solvent-free oxidative chemical vapor deposition process on glass substrates. The metal center (M = NiII, CuII, ZnII, CoII, PdII, FeIIICl, 2H) in the 5,15-disubstituted porphyrin monomer affects the initial C–C coupling step and consequently the formation of triply or doubly linked porphyrin tapes as well as the interchain interaction in the tape as shown by optical spectroscopy, high resolution mass spectrometry and X-ray photoelectron spectroscopy. Optical spectroscopy and conductive atomic force microscopy reveal that these factors influence the near-infrared absorbance and the electrical conductivity of the films. Consequently, the metal ion of the metalloporphyrin allows tuning of the macroscopic properties of the thin films composed of metalloporphyrin tapes.	en_GB
dc.identifier.doi	http://doi.org/10.25358/openscience-6250
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/6260
dc.language.iso	eng	de
dc.rights	CC-BY-NC-ND-4.0	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Constitution and conductivity of metalloporphyrin tapes	en_GB
dc.type	Zeitschriftenaufsatz	de
jgu.journal.title	European journal of inorganic chemistry	de
jgu.journal.volume	20	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.name	Johannes Gutenberg-Universität Mainz
jgu.organisation.number	7950
jgu.organisation.place	Mainz
jgu.organisation.ror	https://ror.org/023b0x485
jgu.pages.end	1945	de
jgu.pages.start	1938	de
jgu.publisher.doi	10.1002/ejic.202000243
jgu.publisher.issn	1099-0682	de
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.uri	https://doi.org/10.1002/ejic.202000243	de
jgu.publisher.year	2020
jgu.rights.accessrights	openAccess
jgu.subject.ddccode	540	de
jgu.type.dinitype	Article	en_GB
jgu.type.resource	Text	de
jgu.type.version	Published version	de

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