Constitution and conductivity of metalloporphyrin tapes

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dc.contributor.authorBengasi, Giuseppe
dc.contributor.authorQuétu, Louise
dc.contributor.authorBaba, Kamal
dc.contributor.authorOst, Alexander
dc.contributor.authorCosas Fernandes, João P.
dc.contributor.authorGrysan, Patrick
dc.contributor.authorHeinze, Katja
dc.contributor.authorBoscher, Nicolas D.
dc.date.accessioned2021-08-09T09:20:31Z
dc.date.available2021-08-09T09:20:31Z
dc.date.issued2020
dc.description.abstractMetalloporphyrin tapes form in a solvent-free oxidative chemical vapor deposition process on glass substrates. The metal center (M = NiII, CuII, ZnII, CoII, PdII, FeIIICl, 2H) in the 5,15-disubstituted porphyrin monomer affects the initial C–C coupling step and consequently the formation of triply or doubly linked porphyrin tapes as well as the interchain interaction in the tape as shown by optical spectroscopy, high resolution mass spectrometry and X-ray photoelectron spectroscopy. Optical spectroscopy and conductive atomic force microscopy reveal that these factors influence the near-infrared absorbance and the electrical conductivity of the films. Consequently, the metal ion of the metalloporphyrin allows tuning of the macroscopic properties of the thin films composed of metalloporphyrin tapes.en_GB
dc.identifier.doihttp://doi.org/10.25358/openscience-6250
dc.identifier.urihttps://openscience.ub.uni-mainz.de/handle/20.500.12030/6260
dc.language.isoeng
dc.rightsCC-BY-NC-ND-4.0
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540 Chemiede_DE
dc.subject.ddc540 Chemistry and allied sciencesen_GB
dc.titleConstitution and conductivity of metalloporphyrin tapesen_GB
dc.typeZeitschriftenaufsatzde_DE
jgu.apc.pricePAR-Fee
jgu.journal.titleEuropean journal of inorganic chemistry
jgu.journal.volume20
jgu.organisation.departmentFB 09 Chemie, Pharmazie u. Geowissensch.de_DE
jgu.organisation.nameJohannes Gutenberg-Universität Mainzde_DE
jgu.organisation.number7950
jgu.organisation.placeMainz
jgu.organisation.rorhttps://ror.org/023b0x485
jgu.pages.end1945
jgu.pages.start1938
jgu.publisher.doi10.1002/ejic.202000243
jgu.publisher.issn1099-0682
jgu.publisher.nameWiley-VCH
jgu.publisher.placeWeinheim
jgu.publisher.urihttps://doi.org/10.1002/ejic.202000243
jgu.publisher.year2020
jgu.rights.accessrightsopenAccessen_GB
jgu.subject.ddccode540
jgu.type.dinitypeArticleen_GB
jgu.type.resourceTexten_GB
jgu.type.versionPublished versionen_GB

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