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Authors: Lüpke, Anne
Carrella, Luca M.
Rentschler, Eva
Title: Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown
Online publication date: 25-Jun-2021
Language: english
Abstract: In this work, we report on a long-sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ2-piv)3[9-MCCr(III)N(shi)-3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9-MC-3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
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Journal: Chemistry - a European journal
Pages or article number: 4283
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2021
ISSN: 1521-3765
Publisher URL:
Publisher DOI: 10.1002/chem.202004947
Appears in collections:JGU-Publikationen

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