Authors:	Lüpke, Anne Carrella, Luca M. Rentschler, Eva
Title:	Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown
Online publication date:	25-Jun-2021
Year of first publication:	2021
Language:	english
Abstract:	In this work, we report on a long-sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ2-piv)3[9-MCCr(III)N(shi)-3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9-MC-3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-6021
Version:	Published version
Publication type:	Zeitschriftenaufsatz
License:	CC BY-NC-ND
Information on rights of use:	https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal:	Chemistry - a European journal 27 13
Pages or article number:	4283 4286
Publisher:	Wiley-VCH
Publisher place:	Weinheim
Issue date:	2021
ISSN:	1521-3765
Publisher URL:	https://doi.org/10.1002/chem.202004947
Publisher DOI:	10.1002/chem.202004947
Appears in collections:	JGU-Publikationen