Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown

Lüpke, Anne; Carrella, Luca M.; Rentschler, Eva

Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown

dc.contributor.author	Lüpke, Anne
dc.contributor.author	Carrella, Luca M.
dc.contributor.author	Rentschler, Eva
dc.date.accessioned	2021-06-25T09:26:50Z
dc.date.available	2021-06-25T09:26:50Z
dc.date.issued	2021
dc.description.abstract	In this work, we report on a long-sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ2-piv)3[9-MCCr(III)N(shi)-3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9-MC-3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state.	en_GB
dc.identifier.doi	http://doi.org/10.25358/openscience-6021
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/6030
dc.language.iso	eng	de
dc.rights	CC-BY-NC-ND-4.0	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown	en_GB
dc.type	Zeitschriftenaufsatz	de
jgu.journal.issue	13	de
jgu.journal.title	Chemistry - a European journal	de
jgu.journal.volume	27	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.name	Johannes Gutenberg-Universität Mainz
jgu.organisation.number	7950
jgu.organisation.place	Mainz
jgu.organisation.ror	https://ror.org/023b0x485
jgu.pages.end	4286	de
jgu.pages.start	4283	de
jgu.publisher.doi	10.1002/chem.202004947
jgu.publisher.issn	1521-3765	de
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.uri	https://doi.org/10.1002/chem.202004947	de
jgu.publisher.year	2021
jgu.rights.accessrights	openAccess
jgu.subject.ddccode	540	de
jgu.type.dinitype	Article	en_GB
jgu.type.resource	Text	de
jgu.type.version	Published version	de

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