The oxidation of organo-boron compounds using electrochemically generated peroxodicarbonate
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Abstract
Peroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state-of-the-art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as green oxidizer in deborolative hydroxylations. A plethora of phenols and alcohols have thus been synthesized in up to 99 % from organoboron compounds using only green and non-toxic solvents. This transformation was successfully scaled-up to multi-gram batch sizes.
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European journal of organic chemistry, 26, 17, Wiley-VCH, Weinheim, 2023, https://doi.org/10.1002/ejoc.202300220