The oxidation of organo-boron compounds using electrochemically generated peroxodicarbonate

dc.contributor.authorKohlpaintner, Philipp J.
dc.contributor.authorMarquart, Lucas
dc.contributor.authorGooßen, Lukas J.
dc.contributor.authorWaldvogel, Siegfried R.
dc.date.accessioned2023-08-03T07:34:37Z
dc.date.available2023-08-03T07:34:37Z
dc.date.issued2023
dc.description.abstractPeroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state-of-the-art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as green oxidizer in deborolative hydroxylations. A plethora of phenols and alcohols have thus been synthesized in up to 99 % from organoboron compounds using only green and non-toxic solvents. This transformation was successfully scaled-up to multi-gram batch sizes.en_GB
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG)|491381577|Open-Access-Publikationskosten 2022–2024 Universität Mainz - Universitätsmedizin
dc.identifier.doihttp://doi.org/10.25358/openscience-9308
dc.identifier.urihttps://openscience.ub.uni-mainz.de/handle/20.500.12030/9326
dc.language.isoengde
dc.rightsCC-BY-4.0*
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subject.ddc540 Chemiede_DE
dc.subject.ddc540 Chemistry and allied sciencesen_GB
dc.titleThe oxidation of organo-boron compounds using electrochemically generated peroxodicarbonateen_GB
dc.typeZeitschriftenaufsatzde
jgu.journal.issue17de
jgu.journal.titleEuropean journal of organic chemistryde
jgu.journal.volume26de
jgu.organisation.departmentFB 09 Chemie, Pharmazie u. Geowissensch.de
jgu.organisation.nameJohannes Gutenberg-Universität Mainz
jgu.organisation.number7950
jgu.organisation.placeMainz
jgu.organisation.rorhttps://ror.org/023b0x485
jgu.pages.alternativee202300220de
jgu.publisher.doi10.1002/ejoc.202300220de
jgu.publisher.issn1099-0690de
jgu.publisher.nameWiley-VCHde
jgu.publisher.placeWeinheimde
jgu.publisher.year2023
jgu.rights.accessrightsopenAccess
jgu.subject.ddccode540de
jgu.subject.dfgNaturwissenschaftende
jgu.type.dinitypeArticleen_GB
jgu.type.resourceTextde
jgu.type.versionPublished versionde

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