The oxidation of organo-boron compounds using electrochemically generated peroxodicarbonate
dc.contributor.author | Kohlpaintner, Philipp J. | |
dc.contributor.author | Marquart, Lucas | |
dc.contributor.author | Gooßen, Lukas J. | |
dc.contributor.author | Waldvogel, Siegfried R. | |
dc.date.accessioned | 2023-08-03T07:34:37Z | |
dc.date.available | 2023-08-03T07:34:37Z | |
dc.date.issued | 2023 | |
dc.description.abstract | Peroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state-of-the-art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as green oxidizer in deborolative hydroxylations. A plethora of phenols and alcohols have thus been synthesized in up to 99 % from organoboron compounds using only green and non-toxic solvents. This transformation was successfully scaled-up to multi-gram batch sizes. | en_GB |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft (DFG)|491381577|Open-Access-Publikationskosten 2022–2024 Universität Mainz - Universitätsmedizin | |
dc.identifier.doi | http://doi.org/10.25358/openscience-9308 | |
dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/9326 | |
dc.language.iso | eng | de |
dc.rights | CC-BY-4.0 | * |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | * |
dc.subject.ddc | 540 Chemie | de_DE |
dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
dc.title | The oxidation of organo-boron compounds using electrochemically generated peroxodicarbonate | en_GB |
dc.type | Zeitschriftenaufsatz | de |
jgu.journal.issue | 17 | de |
jgu.journal.title | European journal of organic chemistry | de |
jgu.journal.volume | 26 | de |
jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
jgu.organisation.number | 7950 | |
jgu.organisation.place | Mainz | |
jgu.organisation.ror | https://ror.org/023b0x485 | |
jgu.pages.alternative | e202300220 | de |
jgu.publisher.doi | 10.1002/ejoc.202300220 | de |
jgu.publisher.issn | 1099-0690 | de |
jgu.publisher.name | Wiley-VCH | de |
jgu.publisher.place | Weinheim | de |
jgu.publisher.year | 2023 | |
jgu.rights.accessrights | openAccess | |
jgu.subject.ddccode | 540 | de |
jgu.subject.dfg | Naturwissenschaften | de |
jgu.type.dinitype | Article | en_GB |
jgu.type.resource | Text | de |
jgu.type.version | Published version | de |