Authors:	Kohlpaintner, Philipp J. Marquart, Lucas Gooßen, Lukas J. Waldvogel, Siegfried R.
Title:	The oxidation of organo-boron compounds using electrochemically generated peroxodicarbonate
Online publication date:	3-Aug-2023
Year of first publication:	2023
Language:	english
Abstract:	Peroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state-of-the-art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as green oxidizer in deborolative hydroxylations. A plethora of phenols and alcohols have thus been synthesized in up to 99 % from organoboron compounds using only green and non-toxic solvents. This transformation was successfully scaled-up to multi-gram batch sizes.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-9308
Version:	Published version
Publication type:	Zeitschriftenaufsatz
License:	CC BY
Information on rights of use:	https://creativecommons.org/licenses/by/4.0/
Journal:	European journal of organic chemistry 26 17
Pages or article number:	e202300220
Publisher:	Wiley-VCH
Publisher place:	Weinheim
Issue date:	2023
ISSN:	1099-0690
Publisher DOI:	10.1002/ejoc.202300220
Appears in collections:	DFG-491381577-H