5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate
| dc.contributor.author | Dassonneville, Benjamin | |
| dc.contributor.author | Schollmeyer, Dieter | |
| dc.contributor.author | Detert, Heiner | |
| dc.date.accessioned | 2025-12-01T10:08:46Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | Rhodium-catalyzed [2+2+2] cycloaddition of carbon disulfide to o,N-dialkynyltosylanilines gives two isomeric indolothiopyranthiones, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent molecule of dichloromethane in the asymmetric unit, C24H17NO2S3·CH2Cl2. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent molecules fill the space between the strands. | en |
| dc.identifier.doi | https://doi.org/10.25358/openscience-13739 | |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/13760 | |
| dc.language.iso | eng | |
| dc.rights | CC-BY-4.0 | |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject.ddc | 540 Chemie | de |
| dc.subject.ddc | 540 Chemistry and allied sciences | en |
| dc.title | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate | en |
| dc.type | Zeitschriftenaufsatz | |
| elements.depositor.primary-group-descriptor | Fachbereich Chemie, Pharmazie und Geowissenschaften | |
| elements.object.id | 291904 | |
| elements.object.labels | annulated heterocycles | |
| elements.object.labels | crystal structure | |
| elements.object.labels | sulfur | |
| elements.object.labels | 3402 Inorganic chemistry | |
| elements.object.type | journal-article | |
| jgu.identifier.uuid | 3a39fbef-7c32-47a6-acc1-99d47ac3a747 | |
| jgu.journal.issue | 5 | |
| jgu.journal.title | IUCrData | |
| jgu.journal.volume | 8 | |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
| jgu.organisation.number | 7950 | |
| jgu.organisation.place | Mainz | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| jgu.pages.alternative | x230354 | |
| jgu.publisher.doi | 10.1107/s2414314623003541 | |
| jgu.publisher.eissn | 2414-3146 | |
| jgu.publisher.licence | CC BY | |
| jgu.publisher.name | IUCr | |
| jgu.publisher.place | Chester | |
| jgu.publisher.year | 2023 | |
| jgu.rights.accessrights | openAccess | |
| jgu.subject.ddccode | 540 | |
| jgu.subject.dfg | Naturwissenschaften | |
| jgu.type.dinitype | Article | en_GB |
| jgu.type.resource | Text | |
| jgu.type.version | Published version |