5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate

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5[4methyl­phen­ylsulfon­yl]1p-20251201110846528704.pdf (541.29 KB)

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2023

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CC-BY-4.0
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Item type: Item , ZeitschriftenaufsatzAccess status: Open Access ,

Abstract

Rhodium-catalyzed [2+2+2] cyclo­addition of carbon di­sulfide to o,N-dialkynyl­tosyl­anilines gives two isomeric indolo­thio­pyran­thio­nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol­ecule of di­chloro­methane in the asymmetric unit, C24H17NO2S3·CH2Cl2. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent mol­ecules fill the space between the strands.

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https://doi.org/10.25358/openscience-13739

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https://openscience.ub.uni-mainz.de/handle/20.500.12030/13760

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IUCrData, 8, 5, IUCr, Chester, 2023, https://doi.org/10.1107/s2414314623003541

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