Authors:	Beck, Alexander D. Haufe, Stefan Waldvogel, Siegfried R.
Title:	General concepts and recent advances in the electrochemical transformation of chloro- and hydrosilanes
Online publication date:	9-Jun-2023
Year of first publication:	2023
Language:	english
Abstract:	Organosilanes play an important role in organic synthesis as well as in a variety of further areas, ranging from life science to transportation. Especially, the electrochemical access has become increasingly important in the past years and developed into an essential topic due to new conceptual approaches and mediated reaction control. With the commercial availability of high-quality electrochemical equipment, the technical requirements for electro-conversion are at hand to a wide audience. This results in the need for a concise survey of electrochemical silane transformation, appropriate for novices as well as experts alike. This review provides an overview of the most relevant work in this field, identifies common obstacles in working with chlorosilanes and hydrosilanes and bridges the gap between known techniques and novel methods with respect to their electrochemical conversion. The historical development is outlined with reference to the various cathodic as well as anodic conversions and should encourage to expand the research field of electrochemical silane transformation.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-9168
Version:	Published version
Publication type:	Zeitschriftenaufsatz
Document type specification:	Scientific article
License:	CC BY
Information on rights of use:	https://creativecommons.org/licenses/by/4.0/
Journal:	ChemElectroChem 10 4
Pages or article number:	202201149
Publisher:	Wiley
Publisher place:	Weinheim
Issue date:	2023
ISSN:	2196-0216
Publisher DOI:	10.1002/celc.202201149
Appears in collections:	DFG-491381577-G