Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-8160
Authors: | Gleede, Barbara Selt, Maximilian Franke, Robert Waldvogel, Siegfried R. |
Title: | Developments in the dehydrogenative electrochemical synthesis of 3,3′,5,5′-tetramethyl-2,2′-biphenol |
Online publication date: | 17-Nov-2022 |
Year of first publication: | 2021 |
Language: | english |
Abstract: | The symmetric biphenol 3,3′,5,5′-tetramethyl-2,2′-biphenol is a well-known ligand building block and is used in transition-metal catalysis. In the literature, there are several synthetic routes for the preparation of this exceptional molecule. Herein, the focus is on the sustainable electrochemical synthesis of 3,3′,5,5′-tetramethyl-2,2′-biphenol. A brief overview of the developmental history of this inconspicuous molecule, which is of great interest for technical applications, but has many challenges for its synthesis, is provided. The electro-organic method is a powerful, sustainable, and efficient alternative to conventional synthesis to obtain this symmetric biphenol up to the kilogram scale. Another section of this article is devoted to different process management strategies in batch-type and flow electrolysis and their respective advantages. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-8160 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Chemistry - a European journal 27 32 |
Pages or article number: | 8252 8263 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2021 |
ISSN: | 1521-3765 |
Publisher DOI: | 10.1002/chem.202005197 |
Appears in collections: | JGU-Publikationen |
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![]() | developments_in_the_dehydroge-20221117100556823.pdf | 771 kB | Adobe PDF | View/Open |