Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-8160
Authors: Gleede, Barbara
Selt, Maximilian
Franke, Robert
Waldvogel, Siegfried R.
Title: Developments in the dehydrogenative electrochemical synthesis of 3,3′,5,5′-tetramethyl-2,2′-biphenol
Online publication date: 17-Nov-2022
Year of first publication: 2021
Language: english
Abstract: The symmetric biphenol 3,3′,5,5′-tetramethyl-2,2′-biphenol is a well-known ligand building block and is used in transition-metal catalysis. In the literature, there are several synthetic routes for the preparation of this exceptional molecule. Herein, the focus is on the sustainable electrochemical synthesis of 3,3′,5,5′-tetramethyl-2,2′-biphenol. A brief overview of the developmental history of this inconspicuous molecule, which is of great interest for technical applications, but has many challenges for its synthesis, is provided. The electro-organic method is a powerful, sustainable, and efficient alternative to conventional synthesis to obtain this symmetric biphenol up to the kilogram scale. Another section of this article is devoted to different process management strategies in batch-type and flow electrolysis and their respective advantages.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
ROR: https://ror.org/023b0x485
DOI: http://doi.org/10.25358/openscience-8160
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
Information on rights of use: https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal: Chemistry - a European journal
27
32
Pages or article number: 8252
8263
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2021
ISSN: 1521-3765
Publisher DOI: 10.1002/chem.202005197
Appears in collections:JGU-Publikationen

Files in This Item:
  File Description SizeFormat
Thumbnail
developments_in_the_dehydroge-20221117100556823.pdf771 kBAdobe PDFView/Open