Gutenberg Open Science: Beyond Kolbe and Hofer–Moest : electrochemical synthesis of carboxylic anhydrides from carboxylic acids

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-8121

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DC Field	Value	Language
dc.contributor.author	Häring, Andreas Peter	-
dc.contributor.author	Pollok, Dennis	-
dc.contributor.author	Strücker, Benjamin R.	-
dc.contributor.author	Kilian, Vincent	-
dc.contributor.author	Schneider, Johannes	-
dc.contributor.author	Waldvogel, Siegfried R.	-
dc.date.accessioned	2022-10-28T09:57:49Z	-
dc.date.available	2022-10-28T09:57:49Z	-
dc.date.issued	2022	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/8136	-
dc.description.abstract	Herein we report a conceptually new non-decarboxylative electrolysis of carboxylic acids to obtain their corresponding anhydrides as highly valuable reagents in organic synthesis. All carbon atoms of the starting material are preserved in the product in an overall redox-neutral reaction. In a broad substrate scope of carboxylic acids the anhydrides are generated with high selectivity, which demonstrates the versatility of the developed method. Beneficially, no dehydrating reagents are required in comparison to conventional methods and the synthesis is based on uncritical starting materials using graphite and stainless steel as very inexpensive and eco-friendly electrode materials.	en_GB
dc.description.sponsorship	Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 491381577	de
dc.language.iso	eng	de
dc.rights	CC BY-NC-ND	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Beyond Kolbe and Hofer–Moest : electrochemical synthesis of carboxylic anhydrides from carboxylic acids	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-8121	-
jgu.type.contenttype	Scientific article	de
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	ChemistryOpen	de
jgu.journal.volume	11	de
jgu.journal.issue	5	de
jgu.pages.alternative	e202200059	de
jgu.publisher.year	2022	-
jgu.publisher.name	Wiley-VCH-Verlag	de
jgu.publisher.place	Weinheim	de
jgu.publisher.issn	2191-1363	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1002/open.202200059	de
jgu.organisation.ror	https://ror.org/023b0x485	-
jgu.subject.dfg	Naturwissenschaften	de
Appears in collections:	DFG-491381577-G

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