Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-8121
Authors: | Häring, Andreas Peter Pollok, Dennis Strücker, Benjamin R. Kilian, Vincent Schneider, Johannes Waldvogel, Siegfried R. |
Title: | Beyond Kolbe and Hofer–Moest : electrochemical synthesis of carboxylic anhydrides from carboxylic acids |
Online publication date: | 28-Oct-2022 |
Year of first publication: | 2022 |
Language: | english |
Abstract: | Herein we report a conceptually new non-decarboxylative electrolysis of carboxylic acids to obtain their corresponding anhydrides as highly valuable reagents in organic synthesis. All carbon atoms of the starting material are preserved in the product in an overall redox-neutral reaction. In a broad substrate scope of carboxylic acids the anhydrides are generated with high selectivity, which demonstrates the versatility of the developed method. Beneficially, no dehydrating reagents are required in comparison to conventional methods and the synthesis is based on uncritical starting materials using graphite and stainless steel as very inexpensive and eco-friendly electrode materials. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-8121 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
Document type specification: | Scientific article |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | ChemistryOpen 11 5 |
Pages or article number: | e202200059 |
Publisher: | Wiley-VCH-Verlag |
Publisher place: | Weinheim |
Issue date: | 2022 |
ISSN: | 2191-1363 |
Publisher DOI: | 10.1002/open.202200059 |
Appears in collections: | DFG-491381577-G |
Files in This Item:
File | Description | Size | Format | ||
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![]() | beyond_kolbe_and_hofermoest__-20221020143437469.pdf | 1.61 MB | Adobe PDF | View/Open |