Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-8037
Authors: | Klein, Martin Waldvogel, Siegfried R. |
Title: | Anodic dehydrogenative cyanamidation of thioethers : simple and sustainable synthesis of N-cyanosulfilimines |
Online publication date: | 8-Nov-2022 |
Year of first publication: | 2021 |
Language: | english |
Abstract: | A novel and very simple to perform electrochemical approach for the synthesis of several N-cyanosulfilimines in good to excellent yields was established. This method provides access to biologically relevant sulfoximines by consecutive oxidation using electro-generated periodate. This route can be easily scaled-up to gram quantities. The S,N coupling is carried out at an inexpensive carbon anode by direct oxidation of sulfide. Therefore, the designed process is atom economic and represents a new “green route” for the synthesis of sulfilimines and sulfoximines. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-8037 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Angewandte Chemie : international edition 60 43 |
Pages or article number: | 23197 23201 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2021 |
ISSN: | 1521-3773 |
Publisher DOI: | 10.1002/anie.202109033 |
Appears in collections: | JGU-Publikationen |
Files in This Item:
File | Description | Size | Format | ||
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![]() | anodic_dehydrogenative_cyanam-20221014171537800.pdf | 1.07 MB | Adobe PDF | View/Open |