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Authors: Röckl, Johannes L.
Schollmeyer, Dieter
Franke, Robert
Waldvogel, Siegfried R.
Title: Dehydrogenative anodic C−C coupling of phenols bearing electron-withdrawing groups
Online publication date: 23-May-2022
Language: english
Abstract: We herein present a metal-free, electrosynthetic method that enables the direct dehydrogenative coupling reactions of phenols carrying electron-withdrawing groups for the first time. The reactions are easy to conduct and scalable, as they are carried out in undivided cells and obviate the necessity for additional supporting electrolyte. As such, this conversion is efficient, practical, and thereby environmentally friendly, as production of waste is minimized. The method features a broad substrate scope, and a variety of functional groups are tolerated, providing easy access to precursors for novel polydentate ligands and even heterocycles such as dibenzofurans.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
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Journal: Angewandte Chemie : international edition
Pages or article number: 315
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2020
ISSN: 1521-3773
Publisher DOI: 10.1002/anie.201910077
Appears in collections:JGU-Publikationen

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