Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-7027
Authors: Nickl, Joachim
Ravelli, Davide
Schollmeyer, Dieter
Waldvogel, Siegfried R.
Title: Straightforward electrochemical sulfonylation of arenes and aniline derivatives using sodium sulfinates
Online publication date: 23-May-2022
Language: english
Abstract: We present a general electrochemical synthesis of sulfones from arenes and aniline derivatives with sodium sulfinates. A wide range of C−S cross-coupling products is available by this oxidant- and transition metal-free method. Both aryl and diaryl sulfones can be readily obtained, using this scalable and inherently safe one-step protocol. Since the synthesis excludes the need for additional supporting electrolyte and occurs in an aqueous electrolyte system that is easily recovered and recycled, this strategy represents a sustainable and green alternative to existing sulfonylation reactions.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
ROR: https://ror.org/023b0x485
DOI: http://doi.org/10.25358/openscience-7027
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
Information on rights of use: https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal: ChemElectroChem
6
17
Pages or article number: 4450
4455
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2019
ISSN: 2196-0216
Publisher DOI: 10.1002/celc.201901212
Appears in collections:JGU-Publikationen

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