Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-7027
Authors: | Nickl, Joachim Ravelli, Davide Schollmeyer, Dieter Waldvogel, Siegfried R. |
Title: | Straightforward electrochemical sulfonylation of arenes and aniline derivatives using sodium sulfinates |
Online publication date: | 23-May-2022 |
Year of first publication: | 2019 |
Language: | english |
Abstract: | We present a general electrochemical synthesis of sulfones from arenes and aniline derivatives with sodium sulfinates. A wide range of C−S cross-coupling products is available by this oxidant- and transition metal-free method. Both aryl and diaryl sulfones can be readily obtained, using this scalable and inherently safe one-step protocol. Since the synthesis excludes the need for additional supporting electrolyte and occurs in an aqueous electrolyte system that is easily recovered and recycled, this strategy represents a sustainable and green alternative to existing sulfonylation reactions. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-7027 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | ChemElectroChem 6 17 |
Pages or article number: | 4450 4455 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2019 |
ISSN: | 2196-0216 |
Publisher DOI: | 10.1002/celc.201901212 |
Appears in collections: | JGU-Publikationen |
Files in This Item:
File | Description | Size | Format | ||
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straightforward_electrochemic-20220523105542910.pdf | 2.44 MB | Adobe PDF | View/Open |