Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6258
Authors: | Wirtanen, Tom Rodrigo, Eduardo Waldvogel, Siegfried R. |
Title: | Selective and scalable electrosynthesis of 2H-2-(aryl)-benzo[d]-1,2,3-triazoles and their N-oxides by using leaded bronze cathodes |
Online publication date: | 11-Aug-2021 |
Year of first publication: | 2020 |
Language: | english |
Abstract: | Electrosynthesis of 2H-2-(aryl)benzo[d]-1,2,3-triazoles and their N-oxides from 2-nitroazobenzene derivatives is reported. The electrolysis is conducted in a very simple undivided cell under constant current conditions with a leaded bronze cathode and a glassy carbon anode. The product distribution between 2H-2-(aryl)benzo[d]-1,2,3-triazoles and their N-oxides can be guided by simply controlling the current density and the amount of the charge applied. The reaction tolerates several sensitive functional groups in reductive electrochemistry. The usefulness and the applicability of the synthetic method is demonstrated by a formal synthesis of an antiviral compound. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-6258 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Chemistry - a European journal 26 25 |
Pages or article number: | 5592 5597 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2020 |
ISSN: | 1521-3765 |
Publisher URL: | https://doi.org/10.1002/chem.201905874 |
Publisher DOI: | 10.1002/chem.201905874 |
Appears in collections: | JGU-Publikationen |
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File | Description | Size | Format | ||
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dr._wirtanen_tom-selective_and_-20210804151231372.pdf | 916.66 kB | Adobe PDF | View/Open |