Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-6248
Authors: Veit, Philipp
Seibert, Sebastian
Förster, Christoph
Heinze, Katja
Title: Unexpected C–C bond formation with a ferrocenyl Fischer carbene complex
Online publication date: 9-Aug-2021
Language: english
Abstract: Thermolysis of (OC)5Cr(C(OEt)(Fc)) (1) gives 2,N-diferrocenyl acetamide Fc–CH2–CO–NH–Fc (2) in the presence of amino ferrocene Fc-NH2. In the absence of a nucleophile, 4-ethoxy-2,3,4-triferrocenyl-cyclobut-2-enone (3) forms from 1 under thermal activation. Single crystal X-ray diffraction, NMR spectroscopy and mass spectrometry unambiguously confirm the structure of both unexpected products. Quantum chemical calculations and kinetic experiments by mass spectrometry and IR spectroscopy help to propose conceivable pathways to their formation.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
ROR: https://ror.org/023b0x485
DOI: http://doi.org/10.25358/openscience-6248
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
Information on rights of use: https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal: Zeitschrift für anorganische und allgemeine Chemie
646
13
Pages or article number: 940
947
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2020
ISSN: 1521-3749
Publisher URL: https://doi.org/10.1002/zaac.201900350
Publisher DOI: 10.1002/zaac.201900350
Appears in collections:JGU-Publikationen

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