Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-6178
Authors: Kehl, Anton
Schupp, Niclas
Breising, Valentina M.
Schollmeyer, Dieter
Waldvogel, Siegfried
Title: Electrochemical synthesis of carbazoles by dehydrogenative coupling reaction
Online publication date: 6-Jul-2021
Language: english
Abstract: A constant current protocol, employing undivided cells, a remarkably low supporting electrolyte concentration, inexpensive electrode materials, and a straightforward precursor synthesis enabling a novel access to N-protected carbazoles by anodic N,C bond formation using directly generated amidyl radicals is reported. Scalability of the reaction is demonstrated and an easy deblocking of the benzoyl protecting group is presented.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
ROR: https://ror.org/023b0x485
DOI: http://doi.org/10.25358/openscience-6178
Version: Published version
Publication type: Zeitschriftenaufsatz
License: CC BY-NC-ND
Information on rights of use: https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal: Chemistry - a European journal
26
68
Pages or article number: 15847
15851
Publisher: Wiley-VCH
Publisher place: Weinheim
Issue date: 2020
ISSN: 1521-3765
Publisher URL: https://doi.org/10.1002/chem.202003430
Publisher DOI: 10.1002/chem.202003430
Appears in collections:JGU-Publikationen

Files in This Item:
  File Description SizeFormat
Thumbnail
kehl_anton-electrochemica-20210705132735420.pdf964.29 kBAdobe PDFView/Open