Electrochemical synthesis of carbazoles by dehydrogenative coupling reaction

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Kehl, Anton
Schupp, Niclas
Breising, Valentina M.
Schollmeyer, Dieter
Waldvogel, Siegfried R.

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ItemZeitschriftenaufsatzOpen Access

Abstract

A constant current protocol, employing undivided cells, a remarkably low supporting electrolyte concentration, inexpensive electrode materials, and a straightforward precursor synthesis enabling a novel access to N-protected carbazoles by anodic N,C bond formation using directly generated amidyl radicals is reported. Scalability of the reaction is demonstrated and an easy deblocking of the benzoyl protecting group is presented.

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Chemistry - a European journal, 26, 68, Wiley-VCH, Weinheim, 2020, https://doi.org/10.1002/chem.202003430

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