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http://doi.org/10.25358/openscience-5241| Authors: | Sarkar, Aritra Kölsch, Jonas C. Berač, Christian M. Venugopal, Akhil Sasmal, Ranjan Otter, Ronja Besenius, Pol George, Subi J. |
| Title: | Impact of NDI‐core substitution on the pH‐responsive nature of peptide‐tethered luminescent supramolecular polymers |
| Online publication date: | 21-Oct-2020 |
| Year of first publication: | 2020 |
| Language: | english |
| Abstract: | The pH‐responsive nature of two self‐assembled NDI‐peptide amphiphile conjugates is reported. The diethoxy substituted NDI showed a pH‐dependent assembly behaviour, as expected. In contrast, the isopropylamino‐ and ethoxy‐substituted NDI based supramolecular polymer was stable at acidic and basic aqueous conditions. This finding highlights how subtle changes in the molecular design of π‐stacked chromophore‐peptide conjugates have a drastic impact on their equilibrium structure and ultimately functional properties. |
| DDC: | 540 Chemie 540 Chemistry and allied sciences |
| Institution: | Johannes Gutenberg-Universität Mainz |
| Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
| Place: | Mainz |
| ROR: | https://ror.org/023b0x485 |
| DOI: | http://doi.org/10.25358/openscience-5241 |
| Version: | Published version |
| Publication type: | Zeitschriftenaufsatz |
| License: | CC BY-NC |
| Information on rights of use: | https://creativecommons.org/licenses/by-nc/4.0/ |
| Journal: | ChemistryOpen 9 3 |
| Pages or article number: | 346 350 |
| Publisher: | Wiley-VCH-Verl. |
| Publisher place: | Weinheim |
| Issue date: | 2020 |
| ISSN: | 2191-1363 |
| Publisher URL: | https://doi.org/10.1002/open.202000017 |
| Publisher DOI: | 10.1002/open.202000017 |
| Appears in collections: | JGU-Publikationen |
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| File | Description | Size | Format | ||
|---|---|---|---|---|---|
 | sarkar_aritra-impact_of_ndi‐-20201021104304986.pdf | 1.8 MB | Adobe PDF | View/Open |