Authors:	Förster, Christoph Dorn, Matthias Reuter, Thomas Otto, Sven Davarci, Güllü Reich, Tobias Carrella, Luca Rentschler, Eva Heinze, Katja
Title:	Ddpd as expanded terpyridine : dramatic effects of symmetry and electronic properties in first row transition metal complexes
Online publication date:	7-Nov-2018
Year of first publication:	2018
Language:	english
Abstract:	The 2,2′:6′:2″-terpyridine ligand has literally shaped the coordination chemistry of transition metal complexes in a plethora of fields. Expansion of the ligand bite by amine functionalities between the pyridine units in the tridentate N,N’-dimethyl-N,N’-dipyridine-2-yl-pyridine-2,6-diamine ligand (ddpd) modifies the properties of corresponding transition metal complexes, comprising redox chemistry, molecular dynamics, magnetism and luminescence. The origins of these differences between ddpd and tpy complexes will be elucidated and comprehensively summarized with respect to first row transition metal complexes with d2–d10 electron configurations. Emerging applications of these ddpd complexes complementary to those of the well-known terpyridine ligand will be highlighted.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-297
Version:	Published version
Publication type:	Zeitschriftenaufsatz
License:	CC BY
Information on rights of use:	https://creativecommons.org/licenses/by/4.0/
Journal:	Inorganics 6 3
Pages or article number:	Art. 86
Publisher:	MDPI
Publisher place:	Basel
Issue date:	2018
ISSN:	2304-6740
Publisher URL:	http://dx.doi.org/10.3390/inorganics6030086
Publisher DOI:	10.3390/inorganics6030086
Appears in collections:	JGU-Publikationen