Protic ferrocenyl ayclic diamino carbene gold(I) complexes
| dc.contributor.author | Waniek, Sven D. | |
| dc.contributor.author | Förster, Christoph | |
| dc.contributor.author | Heinze, Katja | |
| dc.date.accessioned | 2022-10-24T10:15:11Z | |
| dc.date.available | 2022-10-24T10:15:11Z | |
| dc.date.issued | 2022 | |
| dc.description.abstract | Two mononuclear protic ferrocenyl acyclic diamino carbene gold(I) complexes AuCl[C(NHFc)(NR2)] were prepared by nucleophilic attack of diethylamine (R = Et) and diisopropylamine (R = iPr) at the ferrocenyl substituted isocyanide complex chlorido(isocyanoferrocene)gold(I) AuCl(CN−Fc). In the solid state, the multifunctional protic carbene gold(I) complexes display intermolecular aurophilic interactions or intermolecular NH⋅⋅⋅Cl hydrogen bonding in addition to intramolecular non-classical NH⋅⋅⋅Fe hydrogen bonds. Oxidation of the AuCl[C(NHFc)(NR2)] complexes initially takes place at the iron centres giving highly coloured ferrocenium ions, which subsequently likely undergo electron transfer from gold(I) to iron(III) yielding putative EPR-active gold(II) species. | en_GB |
| dc.identifier.doi | http://doi.org/10.25358/openscience-8024 | |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/8039 | |
| dc.language.iso | eng | de |
| dc.rights | CC-BY-NC-ND-4.0 | * |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | Protic ferrocenyl ayclic diamino carbene gold(I) complexes | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| jgu.journal.issue | 2 | de |
| jgu.journal.title | European journal of inorganic chemistry | de |
| jgu.journal.volume | 2022 | de |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
| jgu.organisation.number | 7950 | |
| jgu.organisation.place | Mainz | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| jgu.pages.alternative | e202100905 | de |
| jgu.publisher.doi | 10.1002/ejic.202100905 | de |
| jgu.publisher.issn | 1099-0682 | de |
| jgu.publisher.name | Wiley-VCH | de |
| jgu.publisher.place | Weinheim | de |
| jgu.publisher.year | 2022 | |
| jgu.rights.accessrights | openAccess | |
| jgu.subject.ddccode | 540 | de |
| jgu.type.dinitype | Article | en_GB |
| jgu.type.resource | Text | de |
| jgu.type.version | Published version | de |