Visible-light-induced cleavage of C−S bonds in thioacetals and thioketals with iodine as a photocatalyst
| dc.contributor.author | Krumb, Matthias | |
| dc.contributor.author | Kammer, Lisa Marie | |
| dc.contributor.author | Forster, Robert | |
| dc.contributor.author | Grundke, Caroline | |
| dc.contributor.author | Opatz, Till | |
| dc.date.accessioned | 2022-05-23T08:01:21Z | |
| dc.date.available | 2022-05-23T08:01:21Z | |
| dc.date.issued | 2020 | |
| dc.description.abstract | A protocol for a visible-light-induced cleavage of thioacetals and thioketals using molecular iodine as a photocatalyst in combination with oxygen as the terminal oxidant is reported. The reaction proceeds with low catalyst loadings and high chemical yields while the most commonly used N- and O-protecting groups remain untouched in this transformation. Further investigation showed that the reaction also permits the synthesis of unsymmetrical disulfides by cleavage of unsymmetrical thioacetals. | en_GB |
| dc.identifier.doi | http://doi.org/10.25358/openscience-7021 | |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/7035 | |
| dc.language.iso | eng | de |
| dc.rights | CC-BY-NC-ND-4.0 | * |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | Visible-light-induced cleavage of C−S bonds in thioacetals and thioketals with iodine as a photocatalyst | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| jgu.journal.issue | 2 | de |
| jgu.journal.title | ChemPhotoChem | de |
| jgu.journal.volume | 4 | de |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
| jgu.organisation.number | 7950 | |
| jgu.organisation.place | Mainz | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| jgu.pages.end | 104 | de |
| jgu.pages.start | 101 | de |
| jgu.publisher.doi | 10.1002/cptc.201900231 | de |
| jgu.publisher.issn | 2367-0932 | de |
| jgu.publisher.name | Wiley-VCH | de |
| jgu.publisher.place | Weinheim | de |
| jgu.publisher.year | 2020 | |
| jgu.rights.accessrights | openAccess | |
| jgu.subject.ddccode | 540 | de |
| jgu.type.dinitype | Article | en_GB |
| jgu.type.resource | Text | de |
| jgu.type.version | Published version | de |