Authors:	Batool, Samar Langer, Marcel Myakala, Stephen Nagaraju Heiland, Magdalena Eder, Dominik Streb, Carsten Cherevan, Alexey
Title:	Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites
Online publication date:	5-Dec-2023
Year of first publication:	2023
Language:	english
Abstract:	Thiomolybdates are molecular molybdenum-sulfide clusters formed from Mocenters and sulfur-based ligands. For decades, they have attracted the interestof synthetic chemists due to their unique structures and their relevance inbiological systems, e.g., as reactive sites in enzymes. More recently,thiomolybdates are explored from the catalytic point of view and applied ashomogeneous and molecular mimics of heterogeneous molybdenum sulfidecatalysts. This review summarizes prominent examples ofthiomolybdate-based electro- and photocatalysis and provides acomprehensive analysis of their reactivities under homogeneous andheterogenized conditions. Active sites of thiomolybdates relevant for thehydrogen evolution reaction are examined, aiming to shed light on the linkbetween cluster structure and performance. The shift from solution-phase tosurface-supported thiomolybdates is discussed with a focus on applicationsin electrocatalysis and photocatalysis. The outlook highlights current trendsand emerging areas of thiomolybdate research, ending with a summary ofchallenges and key takeaway messages based on the state-of-the-art research.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-9751
Version:	Published version
Publication type:	Zeitschriftenaufsatz
License:	CC BY
Information on rights of use:	https://creativecommons.org/licenses/by/4.0/
Journal:	Advanced materials Version of Record (VoR)
Pages or article number:	2305730
Publisher:	Wiley-VCH
Publisher place:	Weinheim
Issue date:	2023
ISSN:	1521-4095
Publisher DOI:	10.1002/adma.202305730
Appears in collections:	DFG-491381577-H