Authors:	Nickl, Joachim Ravelli, Davide Schollmeyer, Dieter Waldvogel, Siegfried R.
Title:	Straightforward electrochemical sulfonylation of arenes and aniline derivatives using sodium sulfinates
Online publication date:	23-May-2022
Year of first publication:	2019
Language:	english
Abstract:	We present a general electrochemical synthesis of sulfones from arenes and aniline derivatives with sodium sulfinates. A wide range of C−S cross-coupling products is available by this oxidant- and transition metal-free method. Both aryl and diaryl sulfones can be readily obtained, using this scalable and inherently safe one-step protocol. Since the synthesis excludes the need for additional supporting electrolyte and occurs in an aqueous electrolyte system that is easily recovered and recycled, this strategy represents a sustainable and green alternative to existing sulfonylation reactions.
DDC:	540 Chemie 540 Chemistry and allied sciences
Institution:	Johannes Gutenberg-Universität Mainz
Department:	FB 09 Chemie, Pharmazie u. Geowissensch.
Place:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-7027
Version:	Published version
Publication type:	Zeitschriftenaufsatz
License:	CC BY-NC-ND
Information on rights of use:	https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal:	ChemElectroChem 6 17
Pages or article number:	4450 4455
Publisher:	Wiley-VCH
Publisher place:	Weinheim
Issue date:	2019
ISSN:	2196-0216
Publisher DOI:	10.1002/celc.201901212
Appears in collections:	JGU-Publikationen