Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6021
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DC Field | Value | Language |
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dc.contributor.author | Lüpke, Anne | - |
dc.contributor.author | Carrella, Luca M. | - |
dc.contributor.author | Rentschler, Eva | - |
dc.date.accessioned | 2021-06-25T09:26:50Z | - |
dc.date.available | 2021-06-25T09:26:50Z | - |
dc.date.issued | 2021 | - |
dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/6030 | - |
dc.description.abstract | In this work, we report on a long-sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ2-piv)3[9-MCCr(III)N(shi)-3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9-MC-3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state. | en_GB |
dc.language.iso | eng | de |
dc.rights | CC BY-NC-ND | * |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject.ddc | 540 Chemie | de_DE |
dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
dc.title | Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown | en_GB |
dc.type | Zeitschriftenaufsatz | de |
dc.identifier.doi | http://doi.org/10.25358/openscience-6021 | - |
jgu.type.dinitype | article | en_GB |
jgu.type.version | Published version | de |
jgu.type.resource | Text | de |
jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
jgu.organisation.number | 7950 | - |
jgu.organisation.name | Johannes Gutenberg-Universität Mainz | - |
jgu.rights.accessrights | openAccess | - |
jgu.journal.title | Chemistry - a European journal | de |
jgu.journal.volume | 27 | de |
jgu.journal.issue | 13 | de |
jgu.pages.start | 4283 | de |
jgu.pages.end | 4286 | de |
jgu.publisher.year | 2021 | - |
jgu.publisher.name | Wiley-VCH | de |
jgu.publisher.place | Weinheim | de |
jgu.publisher.uri | https://doi.org/10.1002/chem.202004947 | de |
jgu.publisher.issn | 1521-3765 | de |
jgu.organisation.place | Mainz | - |
jgu.subject.ddccode | 540 | de |
jgu.publisher.doi | 10.1002/chem.202004947 | |
jgu.organisation.ror | https://ror.org/023b0x485 | |
Appears in collections: | JGU-Publikationen |
Files in This Item:
File | Description | Size | Format | ||
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rentschler_eva-filling_the_ga-20210607171834732.pdf | 801.46 kB | Adobe PDF | View/Open |