Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6021
Authors: | Lüpke, Anne Carrella, Luca M. Rentschler, Eva |
Title: | Filling the gap in the metallacrown family : the 9-MC-3 chromium metallacrown |
Online publication date: | 25-Jun-2021 |
Year of first publication: | 2021 |
Language: | english |
Abstract: | In this work, we report on a long-sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ2-piv)3[9-MCCr(III)N(shi)-3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9-MC-3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-6021 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Chemistry - a European journal 27 13 |
Pages or article number: | 4283 4286 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2021 |
ISSN: | 1521-3765 |
Publisher URL: | https://doi.org/10.1002/chem.202004947 |
Publisher DOI: | 10.1002/chem.202004947 |
Appears in collections: | JGU-Publikationen |
Files in This Item:
File | Description | Size | Format | ||
---|---|---|---|---|---|
rentschler_eva-filling_the_ga-20210607171834732.pdf | 801.46 kB | Adobe PDF | View/Open |