Vectorial multichannel-spin-polarimetry and the analysis of spin-transport in metal-organic interfaces

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Abstract

Photoemission spectroscopy has become the key technique for the investigation of electronic properties of promising materials such as Heusler compounds, Weyl systems, materials exhibiting a strong Rashba effect, topological insulators or hybrid metal-organic interfaces. During the last decade photoemission spectroscopy without spin resolution enjoyed a considerable increase in performance due to parallel image detection while the spin polarization analysis of a given electron beam remained time consuming. Since potential candidates for spintronic applications such as metal-organic interfaces tend to degrade within a short period, a massive reduction of spin-resolved data acquisition time is crucial. A newly developed high-performance imaging spin filter system based on a large Ir(001) scattering crystal tackles this issue by enhancing the measurement efficiency. An increase of the effective figure of merit by a factor of over 103 in contrast to standard single-channel detectors is presented together with a detailed characterization of the experimental setup. Furthermore, the spectrometer resolution, spin filter preparation and lifetime are reviewed. An energy and angular resolution of 27 meV and 0.23◦ has been determined for an energy and angular acceptance of 1.5 eV and ±10◦. The spin filter efficiency is analyzed by mapping a broad range of scattering energy and azimuthal angle. A Sherman function of up to 0.44 has been measured under ideal conditions. If the scattering plane coincides with a mirror plane of the crystal, the spin filter is only sensitive to the component of the spin vector perpendicular to the scattering plane. A scattering plane that does not coincide with a crystal mirror plane yields a high sensitivity to spin vector components that are parallel to the scattering plane. A spin rotator element enables the independent determination of the two in-plane components of the spin vector. By combining three or six scattering conditions a vectorial spin analysis becomes possible for both, magnetic and non-magnetic samples. Spin-resolved spectra of Fe/W(110) and H2TPP films of different thickness on Fe/W(110) are measured with the efficient multichannel spin-resolving photoemission spectrometer and with the ESPRESSO spectrometer at the Hiroshima Synchrotron Radiation Center. The experimental results allow for a determination of the spin diffusion length within the molecular film.

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