The overlooked NIR luminescence of Cr(ppy)3
| dc.contributor.author | Stein, Laura | |
| dc.contributor.author | Boden, Pit | |
| dc.contributor.author | Naumann, Robert | |
| dc.contributor.author | Förster, Christoph | |
| dc.contributor.author | Niedner-Schatteburg, Gereon | |
| dc.contributor.author | Heinze, Katja | |
| dc.date.accessioned | 2024-04-18T13:18:01Z | |
| dc.date.available | 2024-04-18T13:18:01Z | |
| dc.date.issued | 2022 | |
| dc.description.abstract | Cr(ppy)3, a structural analog of the green phosphorescent Ir(ppy)3, emits even in solution at room temperature from a weakly distorted spin–flip state at 910 nm (Hppy = 2-phenylpyridine). The low energy arises from an enhanced covalence of the Cr–C bonds as compared to Cr–N bonds. Lower temperature reduces thermally activated decay increasing the emission intensity. | en_GB |
| dc.identifier.doi | http://doi.org/10.25358/openscience-10307 | |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/10325 | |
| dc.language.iso | eng | de |
| dc.rights | CC-BY-4.0 | * |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | The overlooked NIR luminescence of Cr(ppy)3 | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| jgu.journal.issue | 22 | de |
| jgu.journal.title | Chemical communications | de |
| jgu.journal.volume | 58 | de |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
| jgu.organisation.number | 7950 | |
| jgu.organisation.place | Mainz | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| jgu.pages.end | 3704 | de |
| jgu.pages.start | 3701 | de |
| jgu.publisher.doi | 10.1039/D2CC00680D | de |
| jgu.publisher.issn | 1364-548X | de |
| jgu.publisher.name | RSC | de |
| jgu.publisher.place | Cambridge | de |
| jgu.publisher.year | 2022 | |
| jgu.rights.accessrights | openAccess | |
| jgu.subject.ddccode | 540 | de |
| jgu.subject.dfg | Naturwissenschaften | de |
| jgu.type.contenttype | Scientific article | de |
| jgu.type.dinitype | Article | en_GB |
| jgu.type.resource | Text | de |
| jgu.type.version | Published version | de |