In situ formation of an active oxygen evolution catalyst via photodegradation of [Ru(bpy)3]2+

dc.contributor.authorLanger, Marcel
dc.contributor.authorMengele, Alexander K.
dc.contributor.authorMüller, Riccarda
dc.contributor.authorWetzel, Julius C.
dc.contributor.authorMayer, Judith
dc.contributor.authorRau, Sven
dc.contributor.authorStreb, Carsten
dc.date.accessioned2026-01-08T13:14:56Z
dc.date.issued2025
dc.description.abstract[Ru(bpy)3]2+ is a widely used molecular photosensitizer (PS) for light-driven reactions in combination with separate catalysts, although the PS alone is known to promote water oxidation under aqueous conditions as well. In contrast, this behavior has not been reported for organic and aqueous solvent mixtures before. Here, we provide mechanistic insights into the role of [Ru(bpy)3]2+ as PS and oxygen evolution catalyst precursor in organic media. Graphical abstract: In situ formation of an active oxygen evolution catalyst via photodegradation of [Ru(bpy)3]2+en
dc.identifier.doihttps://doi.org/10.25358/openscience-14042
dc.identifier.urihttps://openscience.ub.uni-mainz.de/handle/20.500.12030/14063
dc.language.isoeng
dc.rightsCC-BY-4.0
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540 Chemiede
dc.subject.ddc540 Chemistry and allied sciencesen
dc.titleIn situ formation of an active oxygen evolution catalyst via photodegradation of [Ru(bpy)3]2+en
dc.typeZeitschriftenaufsatz
jgu.identifier.uuid90eff3cb-c59b-4913-bbee-6052b478dd88
jgu.journal.titleDalton transactions
jgu.journal.volume54
jgu.organisation.departmentFB 09 Chemie, Pharmazie u. Geowissensch.
jgu.organisation.nameJohannes Gutenberg-Universität Mainz
jgu.organisation.number7950
jgu.organisation.placeMainz
jgu.organisation.rorhttps://ror.org/023b0x485
jgu.pages.alternative4861
jgu.publisher.doi10.1039/D5DT00233H
jgu.publisher.issn1477-9234
jgu.publisher.nameRSC
jgu.publisher.placeCambridge
jgu.publisher.year2025
jgu.rights.accessrightsopenAccess
jgu.subject.ddccode540
jgu.subject.dfgNaturwissenschaften
jgu.type.dinitypeArticleen_GB
jgu.type.resourceText
jgu.type.versionPublished version

Files

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
in_situ_formation_of_an_activ-20260108141456042506.pdf
Size:
540.66 KB
Format:
Adobe Portable Document Format

License bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
license.txt
Size:
5.14 KB
Format:
Item-specific license agreed upon to submission
Description:

Collections