Substitution effects on the photophysical and photoredox properties of tetraaza[7]helicenes
| dc.contributor.author | Rocker, Johannes | |
| dc.contributor.author | Dresel, Johannes A. | |
| dc.contributor.author | Krieger, Leonie A. | |
| dc.contributor.author | Eckhardt, Paul | |
| dc.contributor.author | Ortuño, Ana M. | |
| dc.contributor.author | Kitzmann, Winald R. | |
| dc.contributor.author | Clever, Guido H. | |
| dc.contributor.author | Heinze, Katja | |
| dc.contributor.author | Opatz, Till | |
| dc.date.accessioned | 2023-09-12T08:15:33Z | |
| dc.date.available | 2023-09-12T08:15:33Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | A series of substituted derivatives of tetraaza[7]helicenes were synthesized and the influence of the substitution on their photophysical and photoredox-catalytic properties was studied. The combination of their high fluorescence quantum yields of up to 0.65 and their circularly polarized luminescence (CPL) activity results in CPL brightness values (BCPL) that are among the highest recorded for [7]helicenes so far. A sulfonylation/hetarylation reaction using cyanopyridines as substrates for photoinduced electron transfer (PET) from the excited helicenes was conducted to test for viability in photoredox catalysis. DFT calculations predict the introduction of electron withdrawing substituents to yield more oxidizing catalysts. | en_GB |
| dc.description.sponsorship | Deutsche Forschungsgemeinschaft (DFG)|491381577|Open-Access-Publikationskosten 2022–2024 Universität Mainz - Universitätsmedizin | |
| dc.identifier.doi | http://doi.org/10.25358/openscience-9522 | |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/9540 | |
| dc.language.iso | eng | de |
| dc.rights | CC-BY-4.0 | * |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | Substitution effects on the photophysical and photoredox properties of tetraaza[7]helicenes | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| jgu.journal.issue | 48 | de |
| jgu.journal.title | Chemistry - a European journal | de |
| jgu.journal.volume | 29 | de |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | |
| jgu.organisation.number | 7950 | |
| jgu.organisation.place | Mainz | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| jgu.pages.alternative | e202301244 | de |
| jgu.publisher.doi | 10.1002/chem.202301244 | de |
| jgu.publisher.issn | 1521-3765 | de |
| jgu.publisher.name | Wiley-VCH | de |
| jgu.publisher.place | Weinheim | de |
| jgu.publisher.year | 2023 | |
| jgu.rights.accessrights | openAccess | |
| jgu.subject.ddccode | 540 | de |
| jgu.subject.dfg | Naturwissenschaften | de |
| jgu.type.dinitype | Article | en_GB |
| jgu.type.resource | Text | de |
| jgu.type.version | Published version | de |