E-Dakin reaction : oxidation of hydroxybenzaldehydes to phenols with electrochemically generated peroxodicarbonate as sustainable ex-cell oxidizer

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dc.contributor.authorSprang, Fiona
dc.contributor.authorSchupp, Niclas
dc.contributor.authorKohlpaintner, Philipp J.
dc.contributor.authorGooßen, Lukas J.
dc.contributor.authorWaldvogel, Siegfried R.
dc.date.accessioned2025-01-09T09:25:53Z
dc.date.available2025-01-09T09:25:53Z
dc.date.issued2024
dc.description.abstractElectrochemically generated peroxodicarbonate solution efficiently oxidizes hydroxybenzaldehydes to valuable phenols. The reaction is carried out in aqueous media without additional solvents or additives. The reaction gives high yields of up to 97% and tolerates a broad variety of substituents, as demonstrated by 20 diverse examples. It was successfully scaled to multi-gram range. This transformation further expands the synthetic applicability of the green oxidizer peroxodicarbonate, which can be generated on demand from ecologically safe carbonate solutions and has a high oxidation potential at mildly basic conditions.en_GB
dc.identifier.doihttp://doi.org/10.25358/openscience-11204
dc.identifier.urihttps://openscience.ub.uni-mainz.de/handle/20.500.12030/11225
dc.language.isoeng
dc.rightsCC-BY-4.0
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540 Chemiede_DE
dc.subject.ddc540 Chemistry and allied sciencesen_GB
dc.titleE-Dakin reaction : oxidation of hydroxybenzaldehydes to phenols with electrochemically generated peroxodicarbonate as sustainable ex-cell oxidizeren_GB
dc.typeZeitschriftenaufsatzde_DE
jgu.apc.netprice0,00
jgu.apc.price0,00
jgu.apc.taxrate19
jgu.apc.transformationcontractRSC
jgu.dfg.year2024
jgu.journal.titleGreen chemistry
jgu.journal.volume26
jgu.nationalcurrency.eur0,00
jgu.organisation.departmentFB 09 Chemie, Pharmazie u. Geowissensch.de_DE
jgu.organisation.nameJohannes Gutenberg-Universität Mainzde_DE
jgu.organisation.number7950
jgu.organisation.placeMainz
jgu.organisation.rorhttps://ror.org/023b0x485
jgu.pages.end5868
jgu.pages.start5862
jgu.publisher.doi10.1039/d3gc04597h
jgu.publisher.issn1463-9270
jgu.publisher.nameRoyal Society of Chemistry
jgu.publisher.placeCambridge
jgu.publisher.year2024
jgu.rights.accessrightsopenAccessen_GB
jgu.subject.ddccode540
jgu.subject.dfgNaturwissenschaftende_DE
jgu.type.dinitypeArticleen_GB
jgu.type.resourceTexten_GB
jgu.type.versionPublished versionen_GB

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