Gutenberg Open Science: A copper-catalyzed synthesis of pyrroles through photochemically generated acylazirines

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-7036

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DC Field	Value	Language
dc.contributor.author	Paternoga, Jan	-
dc.contributor.author	Opatz, Till	-
dc.date.accessioned	2022-05-25T07:56:50Z	-
dc.date.available	2022-05-25T07:56:50Z	-
dc.date.issued	2019	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/7050	-
dc.description.abstract	A synthesis of highly substituted 2,4-diacylpyrroles through a Cu-catalyzed dimerization of acylazirines generated in situ by a photochemical valence isomerization is described. The shown methodology allows the use of simple precursors and a readily available copper(II)-catalyst. Since the reaction is best performed at elevated temperatures, a method to adjust the temperature of the reaction mixture during this dual light and metal-induced process was established. Additionally, mechanistic studies of the reaction were performed in order to provide a deeper understanding of the chemistry of 2-acylazirines.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY-NC-ND	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	A copper-catalyzed synthesis of pyrroles through photochemically generated acylazirines	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-7036	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	European journal of organic chemistry	de
jgu.journal.volume	2019	de
jgu.journal.issue	42	de
jgu.pages.start	7067	de
jgu.pages.end	7078	de
jgu.publisher.year	2019	-
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.issn	1099-0690	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1002/ejoc.201901176	de
jgu.organisation.ror	https://ror.org/023b0x485
Appears in collections:	JGU-Publikationen

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