Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6023Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ludanowski, Simon | - |
| dc.contributor.author | Skarsetz, Oliver | - |
| dc.contributor.author | Creusen, Guido | - |
| dc.contributor.author | Hoenders, Daniel | - |
| dc.contributor.author | Straub, Paula | - |
| dc.contributor.author | Walther, Andreas | - |
| dc.date.accessioned | 2021-06-25T09:56:44Z | - |
| dc.date.available | 2021-06-25T09:56:44Z | - |
| dc.date.issued | 2021 | - |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/6032 | - |
| dc.description.abstract | Responsive materials, such as switchable hydrogels, have been largely engineered for maximum changes between two states. In contrast, adaptive systems target distinct functional plateaus between these maxima. Here, we demonstrate how the photostationary state (PSS) of an E/Z-arylazopyrazole photoswitch can be tuned by the incident wavelength across a wide color spectrum, and how this behavior can be exploited to engineer the photo-dynamic mechanical properties of hydrogels based on multivalent photoswitchable interactions. We show that these hydrogels adapt to the wavelength-dependent PSS and the number of arylazopyrazole units by programmable relationships. Hence, our material design enables the facile adjustment of the mechanical properties without laborious synthetic efforts. The concept goes beyond the classical switching from state A to B, and demonstrates pathways for a truly wavelength-gated adaptation of hydrogel properties potentially useful to engineer cell fate or in soft robotics. | en_GB |
| dc.language.iso | eng | de |
| dc.rights | CC BY-NC-ND | * |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | Wavelength-gated adaptation of hydrogel properties via photo-dynamic multivalency in associative star polymers | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| dc.identifier.doi | http://doi.org/10.25358/openscience-6023 | - |
| jgu.type.dinitype | article | en_GB |
| jgu.type.version | Published version | de |
| jgu.type.resource | Text | de |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
| jgu.organisation.number | 7950 | - |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | - |
| jgu.rights.accessrights | openAccess | - |
| jgu.journal.title | Angewandte Chemie | de |
| jgu.journal.volume | 60 | de |
| jgu.journal.issue | 8 | de |
| jgu.pages.start | 4358 | de |
| jgu.pages.end | 4367 | de |
| jgu.publisher.year | 2021 | - |
| jgu.publisher.name | Wiley-VCH | de |
| jgu.publisher.place | Weinheim | de |
| jgu.publisher.uri | https://doi.org/10.1002/anie.202011592 | de |
| jgu.publisher.issn | 1521-3773 | de |
| jgu.organisation.place | Mainz | - |
| jgu.subject.ddccode | 540 | de |
| jgu.publisher.doi | 10.1002/anie.202011592 | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| Appears in collections: | JGU-Publikationen | |
Files in This Item:
| File | Description | Size | Format | ||
|---|---|---|---|---|---|
 | ludanowski_simon-wavelength-gat-20210607173811166.pdf | 2.61 MB | Adobe PDF | View/Open |