Gutenberg Open Science: Polycyclic Aromatic Hydrocarbons Chemistry in a Spirit of Graphene Engineering

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-5614

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DC Field	Value	Language
dc.contributor.author	Hou, Ian Cheng-Yi	-
dc.date.accessioned	2021-02-17T08:56:12Z	-
dc.date.available	2021-02-17T08:56:12Z	-
dc.date.issued	2021	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/5618	-
dc.description.abstract	Graphene has extraordinary physical and chemical properties. However, it still has its limits. Especially, graphene does not possess a bandgap, which is essential for transistor-based applications. It is believed that proper quantization and defect engineering of graphene can solve such problem. This thesis centres on polycyclic aromatic hydrocarbon (PAH) chemistry related to these topics. The first part describes the synthesis of high molecular weight polyphenylenes, which are structurally suitable precursors for nanographene (NG) with size approaching 5 nm. The second part elaborates in-solution and on-surface synthesis employing azulene derivatives in order to construct carbon nanostructures related to defect architectures observed at graphene grain boundaries. The third part discusses the functionalization of NGs to alter their electronic properties, enable interaction with metal oxide surface, and photoswitchable self-assembly. The thesis aims at providing new insight into bottom-up approach of graphene engineering.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY-ND	*
dc.rights.uri	https://creativecommons.org/licenses/by-nd/4.0/	*
dc.subject.ddc	000 Allgemeines	de_DE
dc.subject.ddc	000 Generalities	en_GB
dc.subject.ddc	500 Naturwissenschaften	de_DE
dc.subject.ddc	500 Natural sciences and mathematics	en_GB
dc.subject.ddc	530 Physik	de_DE
dc.subject.ddc	530 Physics	en_GB
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Polycyclic Aromatic Hydrocarbons Chemistry in a Spirit of Graphene Engineering	en_GB
dc.type	Dissertation	de
dc.identifier.urn	urn:nbn:de:hebis:77-openscience-56869f71-4b1a-4a91-9d45-763b5c4ef5a88	-
dc.identifier.doi	http://doi.org/10.25358/openscience-5614	-
jgu.type.dinitype	doctoralThesis	en_GB
jgu.type.version	Original work	de
jgu.type.resource	Text	de
jgu.date.accepted	2020-09-02	-
jgu.description.extent	258 pages	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.department	MaxPlanck GraduateCenter	de
jgu.organisation.number	7950	-
jgu.organisation.number	9010	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	000	de
jgu.subject.ddccode	500	de
jgu.subject.ddccode	530	de
jgu.subject.ddccode	540	de
jgu.organisation.ror	https://ror.org/023b0x485
Appears in collections:	JGU-Publikationen

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