Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-375Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kammer, Lisa Marie | - |
| dc.contributor.author | Rahman, Aliyaah | - |
| dc.contributor.author | Opatz, Till | - |
| dc.date.accessioned | 2018-04-23T08:17:18Z | - |
| dc.date.available | 2018-04-23T10:17:18Z | - |
| dc.date.issued | 2018 | - |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/377 | - |
| dc.description.abstract | A visible light-promoted protocol for the redox-neutral coupling of N-hydroxyphthalimide esters with different n-heterocyclic compounds is described. the reaction proceeds through an alkyl radical intermediate generated by reductive decarboxylation of n-hydroxyphthalimide esters. in contrast to the original minisci protocol, polyalkylation can largely be avoided. mechanistic investigations revealed a radical chain mechanism which in some cases can proceed even if no photocatalyst is added. this valuable and functional group-tolerant reaction produces substituted heterocycles in moderate to excellent yield. the use of inexpensive starting materials and leds as the light source are key features of this c–c bond formation. | en_GB |
| dc.description.sponsorship | DFG, Open Access-Publizieren Universität Mainz / Universitätsmedizin | - |
| dc.language.iso | eng | - |
| dc.rights | CC BY | de_DE |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
| dc.subject.ddc | 540 Chemie | de_DE |
| dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
| dc.title | A visible light-driven Minisci-type reaction with N-hydroxyphthalimide esters | en_GB |
| dc.type | Zeitschriftenaufsatz | de_DE |
| dc.identifier.doi | http://doi.org/10.25358/openscience-375 | - |
| jgu.type.dinitype | article | - |
| jgu.type.version | Published version | en_GB |
| jgu.type.resource | Text | - |
| jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | - |
| jgu.organisation.number | 7950 | - |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | - |
| jgu.rights.accessrights | openAccess | - |
| jgu.journal.title | Molecules | - |
| jgu.journal.volume | 23 | - |
| jgu.journal.issue | 4 | - |
| jgu.pages.alternative | Art. 764 | - |
| jgu.publisher.year | 2018 | - |
| jgu.publisher.name | MDPI | - |
| jgu.publisher.place | Basel | - |
| jgu.publisher.uri | http://dx.doi.org/10.3390/molecules23040764 | - |
| jgu.publisher.issn | 1420-3049 | - |
| jgu.organisation.place | Mainz | - |
| jgu.subject.ddccode | 540 | - |
| opus.date.accessioned | 2018-04-23T08:17:18Z | - |
| opus.date.modified | 2018-04-23T08:17:33Z | - |
| opus.date.available | 2018-04-23T10:17:18 | - |
| opus.subject.dfgcode | 00-000 | - |
| opus.organisation.string | FB 09: Chemie, Pharmazie und Geowissenschaften: Institut für Organische Chemie | de_DE |
| opus.identifier.opusid | 58101 | - |
| opus.institute.number | 0905 | - |
| opus.metadataonly | false | - |
| opus.type.contenttype | Keine | de_DE |
| opus.type.contenttype | None | en_GB |
| opus.affiliated | Opatz, Till | - |
| jgu.publisher.doi | 10.3390/molecules23040764 | |
| jgu.organisation.ror | https://ror.org/023b0x485 | |
| Appears in collections: | JGU-Publikationen | |
