Autoren:	Ahmadi, Mostafa Jangizehi, Amir Saalwächter, Kay Seiffert, Sebastian
Titel:	Effect of junction aggregation on the dynamics of supramolecular polymers and networks
Online-Publikationsdatum:	23-Feb-2024
Erscheinungsdatum:	2022
Sprache des Dokuments:	Englisch
Zusammenfassung/Abstract:	Transient structures based on associative polymers can deliver complex functions; as such, they hold promise for advanced applications as in drug delivery, tissue engineering, and electronics. The network structure and timescale of its rearrangement are key factors that define their range of utility. However, the inevitable phase separation of polar pairwise associations from nonpolar polymer chains frequently causes junction aggregation, whose stability and functionality significantly affect the network structure and dynamics, and as such, redefine its utility. Engineering the extent of association is a necessity for controlling properties of supramolecular materials, yet the current knowledge of the effect of design parameters on specificities of aggregates and their consequent effects on material properties is limited. To address this gap, the importance of aggregation is highlighted, the available theories and models of the dynamics of associative polymers in the presence of aggregates are reviewed, and the existing experimental records to draw a general guideline for interpreting the effect of aggregates on polymer dynamics are classified. Moreover, pitfalls and considerations like the applicability of time–temperature superposition, and the interplay of kinetics and thermodynamics of aggregation that may undermine the authenticity of the reported data are reviewed.
DDC-Sachgruppe:	540 Chemie 540 Chemistry and allied sciences
Veröffentlichende Institution:	Johannes Gutenberg-Universität Mainz
Organisationseinheit:	FB 09 Chemie, Pharmazie u. Geowissensch.
Veröffentlichungsort:	Mainz
ROR:	https://ror.org/023b0x485
DOI:	http://doi.org/10.25358/openscience-10117
Version:	Published version
Publikationstyp:	Zeitschriftenaufsatz
Weitere Angaben zur Dokumentart:	Review
Nutzungsrechte:	CC BY
Informationen zu den Nutzungsrechten:	https://creativecommons.org/licenses/by/4.0/
Zeitschrift:	Macromolecular chemistry and physics 224 3
Seitenzahl oder Artikelnummer:	2200389
Verlag:	Wiley
Verlagsort:	Weinheim
Erscheinungsdatum:	2022
ISSN:	1521-3935
DOI der Originalveröffentlichung:	10.1002/macp.202200389
Enthalten in den Sammlungen:	DFG-491381577-H