Gutenberg Open Science: Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-9751

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DC Field	Value	Language
dc.contributor.author	Batool, Samar	-
dc.contributor.author	Langer, Marcel	-
dc.contributor.author	Myakala, Stephen Nagaraju	-
dc.contributor.author	Heiland, Magdalena	-
dc.contributor.author	Eder, Dominik	-
dc.contributor.author	Streb, Carsten	-
dc.contributor.author	Cherevan, Alexey	-
dc.date.accessioned	2023-12-05T11:21:35Z	-
dc.date.available	2023-12-05T11:21:35Z	-
dc.date.issued	2023	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/9769	-
dc.description.abstract	Thiomolybdates are molecular molybdenum-sulfide clusters formed from Mocenters and sulfur-based ligands. For decades, they have attracted the interestof synthetic chemists due to their unique structures and their relevance inbiological systems, e.g., as reactive sites in enzymes. More recently,thiomolybdates are explored from the catalytic point of view and applied ashomogeneous and molecular mimics of heterogeneous molybdenum sulfidecatalysts. This review summarizes prominent examples ofthiomolybdate-based electro- and photocatalysis and provides acomprehensive analysis of their reactivities under homogeneous andheterogenized conditions. Active sites of thiomolybdates relevant for thehydrogen evolution reaction are examined, aiming to shed light on the linkbetween cluster structure and performance. The shift from solution-phase tosurface-supported thiomolybdates is discussed with a focus on applicationsin electrocatalysis and photocatalysis. The outlook highlights current trendsand emerging areas of thiomolybdate research, ending with a summary ofchallenges and key takeaway messages based on the state-of-the-art research.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY	*
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-9751	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	Advanced materials	de
jgu.journal.volume	Version of Record (VoR)	de
jgu.pages.alternative	2305730	de
jgu.publisher.year	2023	-
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.issn	1521-4095	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1002/adma.202305730	de
jgu.organisation.ror	https://ror.org/023b0x485	-
jgu.subject.dfg	Naturwissenschaften	de
Appears in collections:	DFG-491381577-H

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