Gutenberg Open Science: The overlooked NIR luminescence of Cr(ppy)3

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-10307

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DC Field	Value	Language
dc.contributor.author	Stein, Laura	-
dc.contributor.author	Boden, Pit	-
dc.contributor.author	Naumann, Robert	-
dc.contributor.author	Förster, Christoph	-
dc.contributor.author	Niedner-Schatteburg, Gereon	-
dc.contributor.author	Heinze, Katja	-
dc.date.accessioned	2024-04-18T13:18:01Z	-
dc.date.available	2024-04-18T13:18:01Z	-
dc.date.issued	2022	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/10325	-
dc.description.abstract	Cr(ppy)3, a structural analog of the green phosphorescent Ir(ppy)3, emits even in solution at room temperature from a weakly distorted spin–flip state at 910 nm (Hppy = 2-phenylpyridine). The low energy arises from an enhanced covalence of the Cr–C bonds as compared to Cr–N bonds. Lower temperature reduces thermally activated decay increasing the emission intensity.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY	*
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	The overlooked NIR luminescence of Cr(ppy)3	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-10307	-
jgu.type.contenttype	Scientific article	de
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	Chemical communications	de
jgu.journal.volume	58	de
jgu.journal.issue	22	de
jgu.pages.start	3701	de
jgu.pages.end	3704	de
jgu.publisher.year	2022	-
jgu.publisher.name	RSC	de
jgu.publisher.place	Cambridge	de
jgu.publisher.issn	1364-548X	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1039/D2CC00680D	de
jgu.organisation.ror	https://ror.org/023b0x485	-
jgu.subject.dfg	Naturwissenschaften	de
Appears in collections:	DFG-491381577-H

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