Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-10058Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Van Dyke, Erik T. | - |
| dc.contributor.author | Eills, James | - |
| dc.contributor.author | Picazo-Frutos, Román | - |
| dc.contributor.author | Sheberstov, Kirill F. | - |
| dc.contributor.author | Hu, Yinan | - |
| dc.contributor.author | Budker, Dmitry | - |
| dc.contributor.author | Barskiy, Danila A. | - |
| dc.date.accessioned | 2024-02-06T15:38:33Z | - |
| dc.date.available | 2024-02-06T15:38:33Z | - |
| dc.date.issued | 2022 | - |
| dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/10076 | - |
| dc.description.abstract | Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) is a rapidly developing form of spectroscopy that provides rich spectroscopic information in the absence of large magnetic fields. However, signal acquisition still requires a mechanism for generating a bulk magnetic moment for detection, and the currently used methods only apply to a limited pool of chemicals or come at prohibitively high cost. We demonstrate that the parahydrogen-based SABRE (signal amplification by reversible exchange)–Relay method can be used as a more general means of generating hyperpolarized analytes for ZULF NMR by observing zero-field J-spectra of [13C]-methanol, [1-13C]-ethanol, and [2-13C]-ethanol in both 13C-isotopically enriched and natural abundance samples. We explore the magnetic field dependence of the SABRE-Relay efficiency and show the existence of a second maximum at 19.0 ± 0.3 mT. Despite presence of water, SABRE-Relay is used to hyperpolarize ethanol extracted from a store-bought sample of vodka (%PH ~ 0.1%). | en_GB |
| dc.language.iso | eng | de |
| dc.rights | CC BY-NC | * |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | * |
| dc.subject.ddc | 530 Physik | de_DE |
| dc.subject.ddc | 530 Physics | en_GB |
| dc.title | Relayed hyperpolarization for zero-field nuclear magnetic resonance | en_GB |
| dc.type | Zeitschriftenaufsatz | de |
| dc.identifier.doi | http://doi.org/10.25358/openscience-10058 | - |
| jgu.type.contenttype | Scientific article | de |
| jgu.type.dinitype | article | en_GB |
| jgu.type.version | Published version | de |
| jgu.type.resource | Text | de |
| jgu.organisation.department | FB 08 Physik, Mathematik u. Informatik | de |
| jgu.organisation.department | Helmholtz Institut Mainz | de |
| jgu.organisation.number | 7940 | - |
| jgu.organisation.number | 9050 | - |
| jgu.organisation.name | Johannes Gutenberg-Universität Mainz | - |
| jgu.rights.accessrights | openAccess | - |
| jgu.journal.title | Science advances | de |
| jgu.journal.volume | 8 | de |
| jgu.journal.issue | 29 | de |
| jgu.pages.alternative | eabp9242 | de |
| jgu.publisher.year | 2022 | - |
| jgu.publisher.name | American Association for the Advancement of Science | de |
| jgu.publisher.place | Washington, DC u.a. | de |
| jgu.publisher.issn | 2375-2548 | de |
| jgu.organisation.place | Mainz | - |
| jgu.subject.ddccode | 530 | de |
| dc.date.updated | 2023-10-17T18:56:45Z | - |
| jgu.publisher.licence | CC BY-NC | - |
| jgu.publisher.doi | 10.1126/sciadv.abp9242 | de |
| elements.object.id | 163925 | - |
| elements.object.type | journal-article | - |
| jgu.organisation.ror | https://ror.org/023b0x485 | - |
| jgu.subject.dfg | Naturwissenschaften | de |
| Appears in collections: | DFG-491381577-G | |
Files in This Item:
| File | Description | Size | Format | ||
|---|---|---|---|---|---|
 | relayed_hyperpolarization_for-20231017205646224.pdf | 703.55 kB | Adobe PDF | View/Open |