Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6253
Authors: | Wirtanen, Tom Rodrigo, Eduardo Waldvogel, Siegfried R. |
Title: | Recent advances in the electrochemical reduction of substrates involving N−O Bonds |
Online publication date: | 9-Aug-2021 |
Year of first publication: | 2020 |
Language: | english |
Abstract: | In this review, the versatile and rich chemistry for the electrochemical reduction of substrates involving N−O bonds is surveyed. By the cathodic treatment of nitro, nitroso and other oxygenated organic nitrogen substrates, versatile and reactive intermediates are formed which can be subsequently converted to high value-added products. In many examples, nitrogen heterocycles are selectively formed, but, also depending on the electrolytic conditions, free oximes, nitrones, amines and other entities can be obtained as well. The recent decades have witnessed two major advances – (i) going directly to more complex target molecules and (ii) conducting the electrolyses in much simpler set-ups. Both improvements make the cathodic access of the target compounds much more practical and scalable. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-6253 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Advanced synthesis & catalysis 362 11 |
Pages or article number: | 2088 2101 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2020 |
ISSN: | 1615-4169 |
Publisher URL: | https://doi.org/10.1002/adsc.202000349 |
Publisher DOI: | 10.1002/adsc.202000349 |
Appears in collections: | JGU-Publikationen |
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File | Description | Size | Format | ||
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![]() | wirtanen_tom-recent_advance-20210804001846034.pdf | 3.42 MB | Adobe PDF | View/Open |