Stability vs. activity in electrocatalytic hydrogen production and magnetic studies of mononuclear labile Cu(ii) and Ni(ii) complexes
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Abstract
In this study, two new mononuclear Schiff base salen-derived complexes, [CuII(H2LMe)]·1.5H2O (C1) and [NiII(H2LMe)]·3H2O (C2), were prepared from 2,6-bis(hydroxymethyl)-4-methylphenol H4L and characterised by single crystal X-ray diffractometry, infrared spectroscopy and elemental analysis. Electrochemical studies in DMF with acetic acid as a proton source revealed catalytic hydrogen evolution activity for both complexes, with C1 displaying higher activity, lower overpotential (η = 0.71 V), and a higher TOFmax of 452 029 s−1 compared to C2 (η = 0.89 V, TOFmax = 986 s−1). The stability of the compounds was tested via controlled potential electrolysis (CPE) and rinse tests, indicating partial heterogeneous contributions to catalysis from electrode-deposited species. These deposits were further analysed by SEM and EDX. To rule out the possibility of nanoparticle formation, dynamic light scattering DLS analysis was performed.
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Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry, 55, 9, RSC, Cambridge, 2026, https://doi.org/10.1039/D6DT00175K