Gutenberg Open Science: 3,7,11-Tris{4-[(1R,3S,4S)-neomenthyloxy]phen-yl}tri[1,2,4]triazolo[4,3-a:4',3'-c:4'',3''-e][1,3,5]triazine-chloroform-ethanol (1/1/1)

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-7965

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DC Field	Value	Language
dc.contributor.author	Herget, Karoline	-
dc.contributor.author	Schollmeyer, Dieter	-
dc.contributor.author	Detert, Heiner	-
dc.date.accessioned	2022-10-13T07:14:49Z	-
dc.date.available	2022-10-13T07:14:49Z	-
dc.date.issued	2013	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/7980	-
dc.description.abstract	The title compound, C54H69N9O3.CHCl3.C2H5OH, was prepared by a threefold nucleophilic substitution of p-neomenthyloxyphenyl-tetra-zole on cyanuric chloride followed by threefold cyclo-elimination of nitro-gen and ring closure. The central tris-triazolotriazine is roughly planar with a maximum deviation of 0.089 (7) A but the adjacent benzene rings are twisted out of this plane. N-C-C-C torsion angles of -80.2 (9), 159.3 (7) and 50.6 (10) degrees destroy the formal C3 symmetry. Cavities are found between the phen-oxy residues: one is occupied by a chloro-form mol-ecule, another by ethanol forming a hydrogen bond to a triazole ring while two isopropyl groups point into the third void. One methyl group and the chloro-frm mol-ecule are disorderd and were refined using a split model.	en_GB
dc.description.sponsorship	DFG, Open Access-Publizieren Universität Mainz / Universitätsmedizin	de
dc.language.iso	eng	de
dc.rights	CC BY	*
dc.rights.uri	https://creativecommons.org/licenses/by/2.0/uk/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	3,7,11-Tris{4-[(1R,3S,4S)-neomenthyloxy]phen-yl}tri[1,2,4]triazolo[4,3-a:4',3'-c:4'',3''-e][1,3,5]triazine-chloroform-ethanol (1/1/1)	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-7965	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	Acta crystallographica : Section E, Structure reports online	de
jgu.journal.volume	69	de
jgu.journal.issue	3	de
jgu.pages.alternative	o365-o366	de
jgu.publisher.year	2013	-
jgu.publisher.name	Munksgaard	de
jgu.publisher.place	Copenhagen	de
jgu.publisher.uri	http://dx.doi.org/10.1107/S1600536813003498	de
jgu.publisher.issn	1600-5368	de
jgu.organisation.place	Mainz	-
jgu.identifier.pmid	23476555	-
jgu.subject.ddccode	540	de
opus.date.modified	2018-08-06T10:30:17Z	-
opus.subject.dfgcode	00-000	-
opus.organisation.string	FB 09: Chemie, Pharmazie und Geowissenschaften: Institut für Organische Chemie	de_DE
opus.identifier.opusid	25263	-
opus.importsource	pubmed	-
opus.institute.number	0905	-
opus.metadataonly	false	-
opus.type.contenttype	Keine	de_DE
opus.type.contenttype	None	en_EN
opus.affiliated	Schollmeyer, Dieter	-
opus.affiliated	Detert, Heiner	-
jgu.publisher.doi	10.1107/S1600536813003498	de
jgu.organisation.ror	https://ror.org/023b0x485	-
Appears in collections:	DFG-OA-Publizieren (2012 - 2017)

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