Gutenberg Open Science: Solvent-dependent facile synthesis of diaryl selenides and biphenols employing selenium dioxide

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-7943

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DC Field	Value	Language
dc.contributor.author	Mirion, Michael	-
dc.contributor.author	Quell, Thomas	-
dc.contributor.author	Schollmeyer, Dieter	-
dc.contributor.author	Dyballa, Katrin M.	-
dc.contributor.author	Franke, Robert	-
dc.contributor.author	Waldvogel, Siegfried R.	-
dc.date.accessioned	2022-10-12T09:51:00Z	-
dc.date.available	2022-10-12T09:51:00Z	-
dc.date.issued	2016	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/7958	-
dc.description.abstract	Biphenols are important structure motifs for ligand systems in organic catalysis and are therefore included in the category of so-called “privileged ligands”. We have developed a new synthetic pathway to construct these structures by the use of selenium dioxide, a stable, powerful, and commercially available oxidizer. Our new, and easy to perform protocol gives rise to biphenols and diaryl selenides depending on the solvent employed. Oxidative treatment of phenols in acetic acid yields the corresponding biphenols, whereas conversion in pyridine results in the preferred formation of diaryl selenides. As a consequence, we were able to isolate a broad scope of novel diaryl selenides, which could act as pincer-like ligands with further applications in organic synthesis or as ligands in transition metal catalysis.	en_GB
dc.description.sponsorship	DFG, Open Access-Publizieren Universität Mainz / Universitätsmedizin	de
dc.language.iso	eng	de
dc.rights	CC BY-NC-ND	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Solvent-dependent facile synthesis of diaryl selenides and biphenols employing selenium dioxide	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-7943	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	ChemistryOpen	de
jgu.journal.volume	5	de
jgu.journal.issue	2	de
jgu.pages.start	115	de
jgu.pages.end	119	de
jgu.publisher.year	2016	-
jgu.publisher.name	Wiley-VCH-Verl.	de
jgu.publisher.place	Weinheim	de
jgu.publisher.uri	http://dx.doi.org/10.1002/open.201500206	de
jgu.publisher.issn	2191-1363	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
opus.date.modified	2018-08-22T09:52:09Z	-
opus.subject.dfgcode	00-000	-
opus.organisation.string	FB 09: Chemie, Pharmazie und Geowissenschaften: Institut für Organische Chemie	de_DE
opus.identifier.opusid	52846	-
opus.institute.number	0905	-
opus.metadataonly	false	-
opus.type.contenttype	Keine	de_DE
opus.type.contenttype	None	en_EN
opus.affiliated	Schollmeyer, Dieter	-
jgu.publisher.doi	10.1002/open.201500206	de
jgu.organisation.ror	https://ror.org/023b0x485	-
Appears in collections:	DFG-OA-Publizieren (2012 - 2017)

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