Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-7021
Authors: | Krumb, Matthias Kammer, Lisa Marie Forster, Robert Grundke, Caroline Opatz, Till |
Title: | Visible-light-induced cleavage of C−S bonds in thioacetals and thioketals with iodine as a photocatalyst |
Online publication date: | 23-May-2022 |
Year of first publication: | 2020 |
Language: | english |
Abstract: | A protocol for a visible-light-induced cleavage of thioacetals and thioketals using molecular iodine as a photocatalyst in combination with oxygen as the terminal oxidant is reported. The reaction proceeds with low catalyst loadings and high chemical yields while the most commonly used N- and O-protecting groups remain untouched in this transformation. Further investigation showed that the reaction also permits the synthesis of unsymmetrical disulfides by cleavage of unsymmetrical thioacetals. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-7021 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | ChemPhotoChem 4 2 |
Pages or article number: | 101 104 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2020 |
ISSN: | 2367-0932 |
Publisher DOI: | 10.1002/cptc.201900231 |
Appears in collections: | JGU-Publikationen |
Files in This Item:
File | Description | Size | Format | ||
---|---|---|---|---|---|
visiblelightinduced_cleavage_-20220523095756058.pdf | 2.01 MB | Adobe PDF | View/Open |