Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-6248
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dc.contributor.authorVeit, Philipp-
dc.contributor.authorSeibert, Sebastian-
dc.contributor.authorFörster, Christoph-
dc.contributor.authorHeinze, Katja-
dc.date.accessioned2021-08-09T08:26:29Z-
dc.date.available2021-08-09T08:26:29Z-
dc.date.issued2020-
dc.identifier.urihttps://openscience.ub.uni-mainz.de/handle/20.500.12030/6258-
dc.description.abstractThermolysis of (OC)5Cr(C(OEt)(Fc)) (1) gives 2,N-diferrocenyl acetamide Fc–CH2–CO–NH–Fc (2) in the presence of amino ferrocene Fc-NH2. In the absence of a nucleophile, 4-ethoxy-2,3,4-triferrocenyl-cyclobut-2-enone (3) forms from 1 under thermal activation. Single crystal X-ray diffraction, NMR spectroscopy and mass spectrometry unambiguously confirm the structure of both unexpected products. Quantum chemical calculations and kinetic experiments by mass spectrometry and IR spectroscopy help to propose conceivable pathways to their formation.en_GB
dc.language.isoengde
dc.rightsCC BY-NC-ND*
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.ddc540 Chemiede_DE
dc.subject.ddc540 Chemistry and allied sciencesen_GB
dc.titleUnexpected C–C bond formation with a ferrocenyl Fischer carbene complexen_GB
dc.typeZeitschriftenaufsatzde
dc.identifier.doihttp://doi.org/10.25358/openscience-6248-
jgu.type.dinitypearticleen_GB
jgu.type.versionPublished versionde
jgu.type.resourceTextde
jgu.organisation.departmentFB 09 Chemie, Pharmazie u. Geowissensch.de
jgu.organisation.number7950-
jgu.organisation.nameJohannes Gutenberg-Universität Mainz-
jgu.rights.accessrightsopenAccess-
jgu.journal.titleZeitschrift für anorganische und allgemeine Chemiede
jgu.journal.volume646de
jgu.journal.issue13de
jgu.pages.start940de
jgu.pages.end947de
jgu.publisher.year2020-
jgu.publisher.nameWiley-VCHde
jgu.publisher.placeWeinheimde
jgu.publisher.urihttps://doi.org/10.1002/zaac.201900350de
jgu.publisher.issn1521-3749de
jgu.organisation.placeMainz-
jgu.subject.ddccode540de
jgu.publisher.doi10.1002/zaac.201900350
jgu.organisation.rorhttps://ror.org/023b0x485
Appears in collections:JGU-Publikationen

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