Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6248
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Veit, Philipp | - |
dc.contributor.author | Seibert, Sebastian | - |
dc.contributor.author | Förster, Christoph | - |
dc.contributor.author | Heinze, Katja | - |
dc.date.accessioned | 2021-08-09T08:26:29Z | - |
dc.date.available | 2021-08-09T08:26:29Z | - |
dc.date.issued | 2020 | - |
dc.identifier.uri | https://openscience.ub.uni-mainz.de/handle/20.500.12030/6258 | - |
dc.description.abstract | Thermolysis of (OC)5Cr(C(OEt)(Fc)) (1) gives 2,N-diferrocenyl acetamide Fc–CH2–CO–NH–Fc (2) in the presence of amino ferrocene Fc-NH2. In the absence of a nucleophile, 4-ethoxy-2,3,4-triferrocenyl-cyclobut-2-enone (3) forms from 1 under thermal activation. Single crystal X-ray diffraction, NMR spectroscopy and mass spectrometry unambiguously confirm the structure of both unexpected products. Quantum chemical calculations and kinetic experiments by mass spectrometry and IR spectroscopy help to propose conceivable pathways to their formation. | en_GB |
dc.language.iso | eng | de |
dc.rights | CC BY-NC-ND | * |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject.ddc | 540 Chemie | de_DE |
dc.subject.ddc | 540 Chemistry and allied sciences | en_GB |
dc.title | Unexpected C–C bond formation with a ferrocenyl Fischer carbene complex | en_GB |
dc.type | Zeitschriftenaufsatz | de |
dc.identifier.doi | http://doi.org/10.25358/openscience-6248 | - |
jgu.type.dinitype | article | en_GB |
jgu.type.version | Published version | de |
jgu.type.resource | Text | de |
jgu.organisation.department | FB 09 Chemie, Pharmazie u. Geowissensch. | de |
jgu.organisation.number | 7950 | - |
jgu.organisation.name | Johannes Gutenberg-Universität Mainz | - |
jgu.rights.accessrights | openAccess | - |
jgu.journal.title | Zeitschrift für anorganische und allgemeine Chemie | de |
jgu.journal.volume | 646 | de |
jgu.journal.issue | 13 | de |
jgu.pages.start | 940 | de |
jgu.pages.end | 947 | de |
jgu.publisher.year | 2020 | - |
jgu.publisher.name | Wiley-VCH | de |
jgu.publisher.place | Weinheim | de |
jgu.publisher.uri | https://doi.org/10.1002/zaac.201900350 | de |
jgu.publisher.issn | 1521-3749 | de |
jgu.organisation.place | Mainz | - |
jgu.subject.ddccode | 540 | de |
jgu.publisher.doi | 10.1002/zaac.201900350 | |
jgu.organisation.ror | https://ror.org/023b0x485 | |
Appears in collections: | JGU-Publikationen |
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File | Description | Size | Format | ||
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veit_philipp-unexpected_c–c-20210803235723729.pdf | 920.73 kB | Adobe PDF | View/Open |