Please use this identifier to cite or link to this item:
http://doi.org/10.25358/openscience-6248
Authors: | Veit, Philipp Seibert, Sebastian Förster, Christoph Heinze, Katja |
Title: | Unexpected C–C bond formation with a ferrocenyl Fischer carbene complex |
Online publication date: | 9-Aug-2021 |
Year of first publication: | 2020 |
Language: | english |
Abstract: | Thermolysis of (OC)5Cr(C(OEt)(Fc)) (1) gives 2,N-diferrocenyl acetamide Fc–CH2–CO–NH–Fc (2) in the presence of amino ferrocene Fc-NH2. In the absence of a nucleophile, 4-ethoxy-2,3,4-triferrocenyl-cyclobut-2-enone (3) forms from 1 under thermal activation. Single crystal X-ray diffraction, NMR spectroscopy and mass spectrometry unambiguously confirm the structure of both unexpected products. Quantum chemical calculations and kinetic experiments by mass spectrometry and IR spectroscopy help to propose conceivable pathways to their formation. |
DDC: | 540 Chemie 540 Chemistry and allied sciences |
Institution: | Johannes Gutenberg-Universität Mainz |
Department: | FB 09 Chemie, Pharmazie u. Geowissensch. |
Place: | Mainz |
ROR: | https://ror.org/023b0x485 |
DOI: | http://doi.org/10.25358/openscience-6248 |
Version: | Published version |
Publication type: | Zeitschriftenaufsatz |
License: | CC BY-NC-ND |
Information on rights of use: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Journal: | Zeitschrift für anorganische und allgemeine Chemie 646 13 |
Pages or article number: | 940 947 |
Publisher: | Wiley-VCH |
Publisher place: | Weinheim |
Issue date: | 2020 |
ISSN: | 1521-3749 |
Publisher URL: | https://doi.org/10.1002/zaac.201900350 |
Publisher DOI: | 10.1002/zaac.201900350 |
Appears in collections: | JGU-Publikationen |
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