Gutenberg Open Science: Metal- and reagent-free electrochemical synthesis of alkyl arylsulfonates in a multi-component reaction

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-6247

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DC Field	Value	Language
dc.contributor.author	Blum, Stephan P.	-
dc.contributor.author	Schollmeyer, Dieter	-
dc.contributor.author	Turks, Maris	-
dc.contributor.author	Waldvogel, Siegfried R.	-
dc.date.accessioned	2021-08-06T10:02:56Z	-
dc.date.available	2021-08-06T10:02:56Z	-
dc.date.issued	2020	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/6257	-
dc.description.abstract	This work presents the first electrochemical preparation of alkyl arylsulfonates by direct anodic oxidation of electron-rich arenes. The reaction mechanism features a multi-component reaction consisting of electron-rich arenes, an alcohol of choice and excess SO2 in an acetonitrile-HFIP reaction mixture. In-situ formed monoalkyl sulfites are considered as key intermediates with bifunctional purpose. Firstly, this species functions as nucleophile and secondly, excellent conductivity is provided. Several primary and secondary alcohols and electron-rich arenes are implemented in this reaction to form the alkyl arylsulfonates in yields up to 73 % with exquisite selectivity. Boron-doped diamond electrodes (BDD) are employed in divided cells, separated by a simple commercially available glass frit.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY-NC-ND	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Metal- and reagent-free electrochemical synthesis of alkyl arylsulfonates in a multi-component reaction	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-6247	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 09 Chemie, Pharmazie u. Geowissensch.	de
jgu.organisation.number	7950	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	Chemistry - a European journal	de
jgu.journal.volume	26	de
jgu.journal.issue	38	de
jgu.pages.start	8358	de
jgu.pages.end	8362	de
jgu.publisher.year	2020	-
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.uri	https://doi.org/10.1002/chem.202001180	de
jgu.publisher.issn	1521-3765	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1002/chem.202001180
jgu.organisation.ror	https://ror.org/023b0x485
Appears in collections:	JGU-Publikationen

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