Gutenberg Open Science: Chemical reaction monitoring using zero-field nuclear magnetic resonance enables study of heterogeneous samples in metal containers

Please use this identifier to cite or link to this item: http://doi.org/10.25358/openscience-6231

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DC Field	Value	Language
dc.contributor.author	Burueva, Dudari B.	-
dc.contributor.author	Eills, James	-
dc.contributor.author	Blanchard, John W.	-
dc.contributor.author	Garcon, Antoine	-
dc.contributor.author	Picazo-Frutos, Román	-
dc.contributor.author	Kovtunov, Kirill V.	-
dc.contributor.author	Koptyug, Igor V.	-
dc.contributor.author	Budker, Dmitry	-
dc.date.accessioned	2021-08-03T08:55:45Z	-
dc.date.available	2021-08-03T08:55:45Z	-
dc.date.issued	2020	-
dc.identifier.uri	https://openscience.ub.uni-mainz.de/handle/20.500.12030/6241	-
dc.description.abstract	We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero-field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two-step hydrogenation of dimethyl acetylenedicarboxylate with para-enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero-field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity.	en_GB
dc.language.iso	eng	de
dc.rights	CC BY-NC	*
dc.rights.uri	https://creativecommons.org/licenses/by-nc/4.0/	*
dc.subject.ddc	530 Physik	de_DE
dc.subject.ddc	530 Physics	en_GB
dc.subject.ddc	540 Chemie	de_DE
dc.subject.ddc	540 Chemistry and allied sciences	en_GB
dc.title	Chemical reaction monitoring using zero-field nuclear magnetic resonance enables study of heterogeneous samples in metal containers	en_GB
dc.type	Zeitschriftenaufsatz	de
dc.identifier.doi	http://doi.org/10.25358/openscience-6231	-
jgu.type.dinitype	article	en_GB
jgu.type.version	Published version	de
jgu.type.resource	Text	de
jgu.organisation.department	FB 08 Physik, Mathematik u. Informatik	de
jgu.organisation.department	Helmholtz Institut Mainz	de
jgu.organisation.number	7940	-
jgu.organisation.number	9050	-
jgu.organisation.name	Johannes Gutenberg-Universität Mainz	-
jgu.rights.accessrights	openAccess	-
jgu.journal.title	Angewandte Chemie	de
jgu.journal.volume	59	de
jgu.journal.issue	39	de
jgu.pages.start	17026	de
jgu.pages.end	17032	de
jgu.publisher.year	2020	-
jgu.publisher.name	Wiley-VCH	de
jgu.publisher.place	Weinheim	de
jgu.publisher.uri	https://doi.org/10.1002/anie.202006266	de
jgu.publisher.issn	1521-3773	de
jgu.organisation.place	Mainz	-
jgu.subject.ddccode	530	de
jgu.subject.ddccode	540	de
jgu.publisher.doi	10.1002/anie.202006266
jgu.organisation.ror	https://ror.org/023b0x485
Appears in collections:	JGU-Publikationen

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